_A2_2 Important Flashcards

0
Q

Equivalence point

A

The point in a titration at which the volume of one solution has reacted exactly with the volume of the second solution

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1
Q

Buffer Solution

A

A Mixture that minimise pH changes on addition of small amounts of acid or base

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2
Q

End point

A

The point in a titration at which there are equal concentrations of the weak acid and conjugate base forms of the indicator

The colours at the end point is midway between the colours of the acid and conjugate base forms

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3
Q

Standard enthalpy change of Neutralisation

AH neut

A

The energy change that accompanies the neutralisation of an aqueous acid by an aqueous base to form one mole of H2O
Under standard conditions

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4
Q

Lattice enthalpy.

A

The enthalpy change that accompanies the formation of one mole of an ionic compound from its gaseous ions under standard conditions

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5
Q

Standard enthalpy change of formation

A

The enthalpy change that takes place when one mole of a compound is formed from its constituent elements in their standard states under standard conditions

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6
Q

enthalpy change of atomisation

A

The enthalpy change that takes place when one mole of gaseous atoms forms from the elements in its standard state

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7
Q

First ionisation energy

A

the energy required to remove one electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions

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8
Q

Second ionisation energy

A

The erngy required to remove one electron from each ION
In one mole of gaseous 1+ ions
To form one mole of gaseous 2+ ions

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9
Q

First electron affinity

A

The enthalpy change accompanying the addition of one electron to each atom in one mole of gaseous atoms to form one mole of gaseous 1- ions

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10
Q

Second electron affinity

A

The enthalpy change accompanying the addition of one electron to each ion in one mole of gaseous1- ions
to form one mole of gaseous 2- ions

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11
Q

Standard enthalpy change of solution

A

The enthalpy change that takes place when one mole of a compound is completely dissolved in water under standard conditions

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12
Q

Standard enthalpy change of hydration

A

The enthalpy change that takes place when one mole of isolated gaseous ions is dissolved in water forming one mole of aqueous ions under standard conditions

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13
Q

Transition element

A

A d block element that forms an ion with an incomplete d subshell

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14
Q

Complex ion

A

A transition metal ion bonded to one or more ligands by coordinate bonds

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15
Q

Ligand

A

A molecule or ion that can donate a pair of electrons with the transition metal ion to form a Coordinate bond

16
Q

Coordination number

A

The total number if coordinate bonds formed between a central metal ion and its ligands

17
Q

Ligand substitution

A

A reaction in which one ligand in a complex ion is replaced by another ligand

18
Q

Bidentate ligand

A

Donates 2 electron pairs/ lone pairs to a metal ion

To form 2 Coordinate bonds