chapter 11 Flashcards

1
Q

what does the functional group of an ether look like

A

an oxygen bonded to 2 carbon atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what is the hybridization of ethers

A

sp3

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

what is the bond angle of ethers

A

109.5

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

describe what at oxirane looks like

A

2 carbons bonded to an o in a ring

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

are ethers polar or non polar

A

they are polar

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

are the dipole dipole attractive forces strong or weak in ethers

A

they are weak in an ether

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

i have an ether and an alcohol which has a higher boiling point

A

alcohol

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

ethers have similar boiling points to…

A

hydrocarbons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

can ethers donate h bonds or accpt h bonds

A

ethers can only accept hydrogen bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

can alcohols accept h bonds or donate or both?

A

alcohols can donate, and accept h bonds !

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

when preparing ethers in the williamson synthesis, yields are higher with what halide

A

primary

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

can williamson synthesis occur with 3 halides

A

no

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

can williamson synthesis occur with 2 halides

A

yes , but it is slower because there is competing elimination

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

what kind of alcohol is preferred for acid catalyzed dehydration of alcohols

A

primary

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

what happens when we have a tertiary alcohol in an acid catalyzed dehydration of alcohol

A

dehydration to an alkene is the only reaction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly