Chp 6—Carbohydrates Flashcards

(49 cards)

1
Q

draw
D-ribose
a-D-ribofuranose

A
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2
Q
A

ribose

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3
Q

draw
D-glucose
a-D-glucopyranose

A
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4
Q
A

glucose

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5
Q

draw
D-galactose
a-D-galactopyranose

A
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6
Q
A

galactose

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7
Q

draw
D-fructose
a-D-fructofuranose

A
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8
Q
A

fructose

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9
Q

draw
D-ribulose
a-D-ribulofuranose

A
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10
Q
A

ribulose

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11
Q

draw
D-mannose
a-D-mannopyranose

A
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12
Q
A

mannose

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13
Q

a-D-glucopyranosyl-(1->4)-a-D-glucopyranose)

name

draw

A

maltose

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14
Q

a-D-glucopyranosyl-(1->1)-a-D-glucopyranose

name

draw

A

trehalose

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15
Q

a-D-glucopyranosyl-(1->2)-B-D-fructofuranose

name

draw

A

sucrose

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16
Q

B-D-galactopyranosyl-(1->4)-D-glucopyranose

name

draw

A

lactose

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17
Q

a-D-glucopyranosyl-(1->6)-a-D-glucopyranose

name

draw

A

isomaltose

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18
Q

starch structure

A
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19
Q

cellulose structure

A
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20
Q

3 C carb

21
Q

4 C carb

22
Q

5 C carb

23
Q

6 C carb

24
Q

sugar L configuation

A

bottom OH on the left

25
sugar D configuration
bottom OH on the right
26
anomers
alpha and beta forms of haworth projection
27
alpha haworth
lowest OH faces down
28
beta haworth
lowest OH faces up
29
5 mem ring
furanose
30
6 mem ring
pyranose
31
for D sugars, CH2OH is pointed...
up on C4 or C5
32
bottom OH on fischer becomes what on haworth?
ether oxygen H goes to the alpha/beta OH
33
carbonyl O on fischer becomes what on haworth?
O of the OH
34
ribose classification
aldopentose
35
glucose classification
aldohexose
36
galactose classification
aldohexose
37
fructose classification
ketohexose
38
ribulose classifcation
ketopentose
39
mannose classification
aldohexose
40
disaccharide nomenclature
sugar-yl-(#C --> #C)-sugar
41
O linked glycosylation
on serione, threonine
42
N linked glycosylation
on asparagine
43
application of glycosylation
drug masking
44
2 types of polysaccharide
hetero homo
45
examples of polysaccharides
starch cellulose peptidoglycan chitin glycogen
46
present on reducing sugars
hemiacetal group OH on same C attached to ether O
47
special about reducing sugars
can be trapped in fischer projection form
48
3 tests for reducing sugars
Benedicts test Fehling's test Tollens test
49
intensity of reducing sugar positive given by.....
number of hemiacetals exposed