DAY 1 Flashcards
demonstrated the relationship of water and cholera
Dr. John Snow
show the relationship of typhoid and water contamination
Dr. William Budd
half life is defined as
ln(0.5)k^-1 or 0.693K-1
Commercial sulfuric acid (H2SO4) is often purchased as a 93 wt% (weight percent) solution. Find
the concentration of this solution of H2SO4 in units of milligram per liter, molarity, and normality. Sulfuric acid (100%) has a specific gravity of 1.839. Assume that the temperature of the
solution is 15◦C.
36.30 Eq / L or 36.3 N
Determine the equivalent weight of each of the following: Ca2+, CO2−
3 , CaCO3
50.05 g · g / Eq or 50.05 mg /mEq
Find the mass of sodium bicarbonate (NaHCO3) that must be added a 1.00 L volumetric flask
containing distilled water to make a 1.0 M solution. Find the normality of the solution.
84 g / L
The pH of a water is measured to be 7.5. The concentration of bicarbonate was measured to be
1.3 × 10−3 M. What are the concentrations of carbonate, carbonic acid, and CT? Assume this system is closed to the atmosphere.
1.384 × 10−3 M ≈ 1.4 × 10−3 M
The pH of a water is measured to be 7.5. What are the concentrations of carbonate, bicarbonate,
carbonic acid, and CT? Assume this system is open to the atmosphere. The temperature is 25◦
C.
The Henry’s constant for carbon dioxide is 10−1.47 M · atm−1 at this temperature. The partial
pressure of carbon dioxide is 10−3.53 atm.
1.70 × 10−4 M ≈ 1.7 × 10−4 M
This ability to resist change is referred to as
buffering capacity
describe a water’s ability to resist changes in pH on the
addition of acid, therefore, it is also called acid-neutralizing capacity
alkalinity
is defined as the sum of all titratable bases to a pH of approximately 4.5.
Alkalinity
A water contains 100.0 mg · L−1 CO2−
3 and 75.0 mg · L−1 HCO−
3 at a pH of 10 (T = 25◦
C).
Calculate the exact alkalinity. Approximate the alkalinity by ignoring the appropriate chemical
species.
233 mg · L−1 as CaCO3
ability of a water to resist changes in pH due to the addition of base. Therefore, it is also called
base-neutralizing capacity.
Acidity
essentially, the extent to which a unit mass of soil can exchange a mass of
a certain ion of interest
Exchange capacity
is essentially the attachment of a chemical to either the mineral or organic portions of soil particles and includes both
adsorption and absorption
Sorption
A soil sample is collected and the soil water is analyzed for the chemical compound 1,2-dichloroethane (DCA). The concentration in the water is found to be 12.5 g · L−1. The organic matter content of the soil is 1.0%. Determine the concentration of DCA that would be sorbed to the soil and that associated with the organic matter. DCA has a Kd of
0.724 (ug · kg−1
)(ug · L−1)−1 .
= 905 ug · kg−1
A 1-m3 sample of air was found to contain 80 g · m−3 of SO2. The temperature and pressure
were 25.0◦
C and 103.193 kPa when the air sample was taken. What was the SO2 concentration in
parts per million?
0.030 ppm of SO2
A solution of sodium bicarbonate is prepared by adding 45.00 g of sodium bicarbonate to a 1.00-L volumetric flask and adding distilled water until it reaches the 1.00-L mark. What is the concentration of
sodium bicarbonate in units of (a) milligrams per liter, (b) molarity, (c) normality and (d) milligrams per
liter as CaCO3?
(a) 4.5 × 104 mg · L−1 (b) 0.536 M (c) 0.536 N (d) 2.68 × 104 mg · L−1 as CaCO3
A magnesium hydroxide solution is prepared by adding 10.00 g of magnesium hydroxide to a volumetric
flask and bringing the final volume to 1.00 L by adding water buffered at a pH of 7.0. What is the concentration of magnesium in this solution? (Assume that the temperature is 25◦
C and the ionic strength is
negligible).
0.17 M
A ferric phosphate solution is prepared by adding 2.4 g of ferric phosphate to a volumetric flask and
bringing the final volume to 1.00 L by adding water having a phosphate concentration of 1.0 mg · L−1 .
What is the concentration of soluble iron in this solution? (Assume that the temperature of the solution is
25◦
C.)
1.20 × 10−17 M
A solution has an H+ concentration of 10−5 M. (a) What is the pH of this solution? (b) What is the pOH?
(Assume that the temperature of the solution is 25◦
C.)
(a) 5 (b) 9
A solution of acetic acid is prepared in water by adding 11.1 g of sodium acetate to a volumetric flask and
bringing the volume to 1.0 L with water. The final pH is measured to be 5.25. What are the concentrations
of acetate and acetic acid in solution? (Assume that the temperature of the solution is 25◦
C.)
[HA] = 0.033 M [A−] = 0.102 M
The concentration of a chemical degrades in water according to first-order kinetics. The degradation
constant is 0.2 day−1
. If the initial concentration is 100.0 mg · L−1, how many days are required for the concentration to reach 0.14 mg · L−1?
32.9 days
Hypochlorous acid decays in the presence of ultraviolet radiation. Assume that degradation occurs according to first-order kinetics and the rate of degradation was measured to be 0.12 day−1 (at a particular sunlight
intensity and temperature). Given this, how long does it take for the concentration of hypochlorous acid to
reach nondetectable levels (0.05 mg · L−1 ) if the initial concentration were 3.65 mg · L−1 ?
35.8 days