IQR 2 Flashcards

(54 cards)

1
Q

Isotopes

A

Atoms of one element that differ by having different numbers of neutrons in their nuclei. The number of protons will remain the same. Isotopes are usually named by their mass.

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2
Q

Atmoic number

A

NUmber of protons

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3
Q

Mass number

A

The avarage mass of all isoptopes nucleus that include protons and neutrons.

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4
Q

Relative atomic mass

A

The average mass of the atoms present in the naturally occurring element relative to the mass of an atom of the carbon-12 isotope, taken as 12 exactly.

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5
Q

Relative molecular mass

A

Mass of a melecule of the compound relative to the mass of an atom.

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6
Q
A

i

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7
Q

Another method of showing nuclear data. What does each character represent.

A

M is the chemical symbol
A is the mass number
z is the Atmoic number

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8
Q

Electron configuration formula

A

2n^2

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9
Q

The elctron cloud

A

Region around the nucleus where elctrons are most likely to be found. Electrons don’t move in fixed orbits but electron clouds with probability regions called orbitals.

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10
Q

Nucleon

A

Sometimes used to describe either a proton or a neutron. The mass number is sometimes called the nucleon number.

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11
Q

Relative abundance

A

Percentage of that isotope in the naturally occurring element.

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12
Q

Electron configuration:

A

Determined by allocating electrons to energy levels

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13
Q

Electron shells

A

Electron level, each cell is split into sub cells: SPDF

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14
Q

Sub cells:

A

1.s
2.sp
3. spd
4.spdf
Every orbital has a maximum of two electrons
Each sub cell has different obital shape and number. Different orbitals have different energies.
Electrons fill the lowest available energy level that they can.
Electrons must fill orbital singularly before they buddy up.

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15
Q

Orbital

A

Volume of space around the atom where one or 2 electrons randomly move.

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16
Q

S orbital

A

Contains 1 orbital
2 electrons
shaped liek a sphere

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17
Q

P orbital

A

3 orbitals
Dumbell shape arranged around axis at 90
6 electrons, 2 per orbital

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18
Q

D orbital

A

5 orbitals,
10 electrons

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19
Q

F orbital

A

7 orbitals
14 electrons

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20
Q

Spin

A

No two electrons can be together with the same spin.

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21
Q

Electron configuration example: Krypton

A
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22
Q

Change in energy

A

Electrons can move between energy levels
Absorb Photons to move to higher energy level- excitation. Emit photons to move to lower energy level de-excitation.
The amount of energy absorbed/emitted by the electron must equal the different between the energy levels involved.

23
Q

Photon

A

A packet of light energy or electromagnetic radiation. Wavelengths determine the colour.

24
Q

Emission spectra

A

When an atom has electrons in higher levels that can move down to lower levels. THey emit phtons with energy based on the difference in electron energy levels. The photons of different colour (energy) will also have a different colour or wavelength.

25
Absorption spectrum
Photos absorbed will have energies that match specific wavelengths. The spectrum of light we see will be missing specific colours.
26
Stable elctron configurations
Noble gases: Completely filled energy levels Akali metals: Similar properties as they loose one electron Halogens: Similar properties as each gains one electron The driving force behind chemical reactivity is so that atoms can achieve the same electron configuration. Elements in the same group tend to gain or loose the same number of electrons transition elemts: 3-12 on table
27
Valence electron and position ont he periodic table:
Number of valence electron to group is number 1,2, 13+ Group 14 can either be +4 or +2
28
Principles
The lowest energy electrons are the ones closest to the nucleus.
29
Bohr theory
Electron move around the nucleus in fixed orbits. When absord energy they moce to orbits of large radius then when emit energy they move to smaller radius. Incorporated Planck's quantum theory: Electrons could only have discrete energy levels Only could be used for simple spectra e.g Hydrogen.
30
Schrodinger:
Treated the electron as a wave rather than a particle Applied mathematics to find location around nucleus (Schrodinger equation). Outcome: Finding the electron atoms anywhere in a spherical shape around the nucleus which contrasted bohrs fixed orbit idea Orbital was introduced when describing the space around the nucleus where your likely to find an electron. When applied to an atom with more than one elctron it leads to sublevels and orbitals. Equation used to interpret emission spectra with many electrons.
31
Positron emission
Involves the emission of a positively charge particle, resulting from the changing of a proton into a neutron. (Happen when there is a surplus of protons) Chemical Symbol is
32
Electron Capture
Opposite of an electron.
33
Ethanol anion
[CH3COO]−
34
Carbonate ion
35
Hydrogen carbonate ion
Also called Bicarbonate
36
Hydroxide Ion
37
Nitrate Ion
38
Phosphate Ion
39
Sulfate Ion
40
Unique about zinc and silver
Always a plus two.
41
Flame test: Lithium
Red
42
Flame test: Sodium
Yellow-Orange
43
Flame test: Potassium
Pink
44
Flame test: Calcium
Orange- red
45
Flame test: Strontium
red
46
Flame test: Barium
Pale green
47
Flame test: Copper
Blue-green
48
Limitations of the flame test
Only distinguishes between substances of a pure compound Some compounds have similar colours Colours are subjective Not all metal ions give colour under a flame.
49
Aufbau's Principle
States that the lowest energy orbitals are always filled with electrons first. Energy levels start to overlap in energy. (Anomaly where 4s is before 3d)
50
Pauli's Exclusion principle
An orbital only holds 2 electrons and the electrons in the same orbital have opposite spin. Because electrons spin, two can occupy one orbital.
51
Hunds rule
Within a sublevel single electrons are placed one at a time in orbitals with spins of the same directions. Then will double up with electrons spinning the opposite direction
52
Noble Gas electron configuration
When electrons configurations are written, noble gas notation is often used to represent filled shells. In noble gas notation, the symbol for a noble gas is written within square brackets in front of the spdf or orbital box notation representing additional electrons. The electron configuration can be abbreviated by indicating the innermost electron electrons with the symbol of the preceding noble gas.
53
Exception to Aufbau rule
1. When orbitals are half-filled or filled by moving electrons
54
Limitations of Bohr's model that lead to shrodinger's model
Bohr model could not interpret complex spectra. Didn't accept that the electron was not just a lump of matter but had wave properties. Schrodinger treated electrons as waves, that moved at high speeds throughout orbitals. Schrodinger created equation which used wave properties to calculate probability of finding an electron at a particular location.