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Organic Chemistry > Mechanisms > Flashcards

Mechanisms Flashcards

1
Q
A

SN2

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2
Q
A

SN1

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3
Q
A

E2

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4
Q
A

E1

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5
Q
A

Williamson ether synthesis

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6
Q
A

Epoxide formation via halohydrin

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7
Q
A

Dehydration of alcohols with acid

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8
Q
A

Conversion of alcohol to alkyl halide with HX

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9
Q
A

Conversion of alcohol to an alkyl bromide with PBr3

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10
Q
A

Conversion of alcohol to an alkyl chloride with SOCl2

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11
Q
A

Conversion of alcohol to a tosylate with tosyl chloride

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12
Q
A

Epoxide opening with strong nucleophile

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13
Q
A

Epoxide opening with acid and weak nucleophile

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14
Q
A

Electrophilic addition of HX

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15
Q
A

Hydration of Alkenes

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16
Q
A

Electrophilic addition of X2

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17
Q
A

Halohydrin formation

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18
Q
A

Hydroboration-oxidation of alkenes

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19
Q
A

Xoymercuration-demercuration of alkenes

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20
Q
A

Epoxidation using peroxy acids

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21
Q
A

Tans dihydroxylation

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22
Q
A

Oxidative cleavage of alkenes (ozonolysis)

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23
Q
A

Oxidative cleavage of alkenes with oxidative workup (ozonolysis)

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24
Q
A

SN2 substitution with acetylide anion

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25
Q
A

Epoxide opening with acetylide anion

26
Q
A

Reduction of alkyne to trans alkene

27
Q
A

Radical bromination of alkenes

28
Q
A

Radical allylic bromination of alkenes

29
Q
A

Radical addition of HBr

30
Q
A

Addition of HX to conjugated dienes (thermodynamic)

31
Q
A

Addition of HX to conjugated dienes (kinetic)

32
Q

Describe the mechanism:

SN2

A
33
Q

Describe the mechanism:

SN1

A
34
Q

Describe the mechanism:

E2

A
35
Q

Describe the mechanism:

E1

A
36
Q

Describe the mechanism:

Williamson ether synthesis

A
37
Q

Describe the mechanism:

Epoxide formation via halohydrin

A
38
Q

Describe the mechanism:

Dehydration of alcohols with acid

A
39
Q

Describe the mechanism:

Conversion of alcohol to alkyl halide with HX

A
40
Q

Describe the mechanism:

Conversion of alcohol to an alkyl bromide with PBr3

A
41
Q

Describe the mechanism:

Conversion of alcohol to an alkyl chloride with SOCl2

A
42
Q

Describe the mechanism:

Conversion of alcohol to a tosylate with tosyl chloride

A
43
Q

Describe the mechanism:

Epoxide opening with strong nucleophile

A
44
Q

Describe the mechanism:

Epoxide opening with acid and weak nucleophile

A
45
Q

Describe the mechanism:

Electrophilic addition of HX

A
46
Q

Describe the mechanism:

Hydration of Alkenes

A
47
Q

Describe the mechanism:

Electrophilic addition of X2

A
48
Q

Describe the mechanism:

Halohydrin formation

A
49
Q

Describe the mechanism:

Hydroboration-oxidation of alkenes

A
50
Q

Describe the mechanism:

Xoymercuration-demercuration of alkenes

A
51
Q

Describe the mechanism:

Epoxidation using peroxy acids

A
52
Q

Describe the mechanism:

Tans dihydroxylation

A
53
Q

Describe the mechanism:

Oxidative cleavage of alkenes (ozonolysis)

A
54
Q

Describe the mechanism:

Oxidative cleavage of alkenes with oxidative workup (ozonolysis)

A
55
Q

Describe the mechanism:

SN2 substitution with acetylide anion

A
56
Q

Describe the mechanism:

Epoxide opening with acetylide anion

A
57
Q

Describe the mechanism:

Reduction of alkyne to trans alkene

A
58
Q

Describe the mechanism:

Radical bromination of alkenes

A
59
Q

Describe the mechanism:

Radical allylic bromination of alkenes

A
60
Q

Describe the mechanism:

Radical addition of HBr

A
61
Q

Describe the mechanism:

Addition of HX to conjugated dienes (thermodynamic)

A
62
Q

Describe the mechanism:

Addition of HX to conjugated dienes (kinetic)

A

Organic Chemistry (2 decks)

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