Module 2: Polarity, Resonance, and Arrow Pushing Flashcards

1
Q

Hydrogen must have two ___________ and no _______________________ can have more than ___________________.

A

electrons
second-row element
eight electrons

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2
Q

Positively charged carbon atoms are called?

A

carbocations

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3
Q

Two resonance structures must have the same number of?

A

unpaired electrons

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4
Q

Some molecules can’t be adequately represented by a single Lewis structure

A

resonance structures

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5
Q

different geometries

A
  1. linear
  2. trigonal planar
  3. tetrahedral
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6
Q

Hybrid Lewis structures = ?

A

resonance structures

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7
Q

resonance structures are represented by a?

A

double-headed arrow

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8
Q

it is the measure of an atom’s attraction for an electron in a bond

A

electronegativity

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9
Q

it always begins at an electron pair (a bond or lone pair)

A

tail

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10
Q

The __________________ is more stable than any resonance structure because it delocalizes electron density over a larger volume.

A

resonance hybrid

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11
Q

it shows where the electrons are coming from

A

tail

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12
Q

Two Lewis structures having the same placement of atoms but a different arrangements of electrons

A

resonance structures

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13
Q

These differ in the arrangement of both atoms and electrons

A

isomers

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14
Q

These are unstable intermediates because they contain a carbon atom that is lacking an octet of electrons

A

carbocations

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15
Q

Resonance structures must be valid _____________________

A

Lewis structures

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16
Q

it is the most electronegative

A

upper right corner

17
Q

These differ only in the way atoms are connected

A

constitutional isomers

18
Q

it shows the movement of an electron pair

A

curved arrow notation

19
Q

These are different compounds that have the same molecular formula

20
Q

different types of bonds

A
  1. single
  2. double
  3. triple
21
Q

It refers to electrons that participates in resonance

A

Delocalized

22
Q

It refers to electrons that does not participate in resonance

24
Q

A quantity called _______________________ indicates the fraction orbital due to the 2s orbital used to form it.

A

percent s-character

25
it shows where the electrons are going
head
26
different hybridizations
1. sp 2. sp2 3. sp3
27
As the number of electrons between two nuclei increases, bonds become ________ and ________
shorter, stronger
28
triple bonds are ________ and _________ than double bonds
shorter, stronger
29
these differ only in the arrangement of the electrons
resonance structures