NS FL#1 Flashcards
(58 cards)
Effect of High Conc of Ingested Salt into the blood
Produce a relatively concentrated, or hypertonic solution. [NaCl doesn’t readily diffuse through the phospholipid bilayer, however water can diffuse via osmosis, resulting in a flow of water out of cell in an attempt for isotonic solution]
Boiling Point is defined as
the temperature at which the vapor pressure of a solution is equal to the atmospheric pressure.
Why does ICE float in water?
Solid ICE is LESS Dense than liquid water due to hydrogen bonding that can occur between water molecules, yielding solid crystalline structure with relatively large amounts of empty space.
Compare polar to solubility (Aldehydes to Carboxylic Acid)
the more polar a compound is, the higher its solubility in aqueous solution. The Carboxylic acid group, if deprotonated, will be much more soluble in water than the aldehyde group.
What separation technique would be used to separate an acidic compound from a fairly neutral one?
An extraction technique with a dilute weak base (such as a solution of sodium bicarbonate)
What is the purpose of using Boiling Chips during distillation?
When transitioning from liquid to gas during boiling, the liquid needs nucleation sites, or places to start forming bubbles. This is typically done by introducing boiling chips
Vacuum distillation is used for
lowering the boiling points of the substances to be distilled
Difference in melting/boiling of Alcohol/Carboxylic Acid/Aldehydes/Ketones
Alcohols and Carboxylic acids have higher melting/boiling pts than aldehydes and ketones due to Hydrogen bonds among them
Equation of a torque
T=Fdsin(theta)
Three ways to increase the Torque applied to an object
- Increase the Force
- Increasing the distance at which the force is applied from the fulcrum
- Adjusting the angle at which the force is applied to make it as close as possible to perpendicular to the lever arm
Newton’s First Law
Inertia. An object remains at rest or at a constant velocity unless an external force acts upon it. Fnet=0
Newton’s Second Law
Force. Total sum of forces acting on an object is equivalent to its mass ties its acceleration. This is the familiar equation of Fnet=ma
Newton’s Third Law
Every reaction has exact equal and opposite reaction. It states that when body A exerts a force on body B, body B exerts an equal and opposite force on body A: Fab=-Fba
What is True about Diatomic Nitrogen Gas?
Diatomic nitrogen gas is relatively inert and can be used as the atmosphere in laboratory conditions to prevent unwanted side reactions.
Bond angle and hybridization of acetone
120; sp2
What reagent could be used to go from Aldehyde to Primary Alcohol?
LiAlH4 is a reducing agent capable of performing this reaction.
A primary alcohol can be be oxidized to an aldehyde by
a mild oxidizing agent (PCC)
A primary alcohol can be be oxidized to Carboxylic Acid by
Strong Oxidizing agent like Na2Cr2O7
What is one strong agent that can reduce Carboxylic Acid to an alcohol
LiAlH4
Name two biological substances that are likely derived from tarpenes?
Aldosterone & Estrogen. They are lipophilic
IR frequency range of Carbonyl (C=O)
1700-1750 cm-1
IR frequency range of OH
3200-3500 cm-1
In the electron transport chain, electrons are passed from
species with less positive reduction potential to those with more positive reduction potential.
One main difference between electrolytic and galvanic cells
In contrast to galvanic cell, an electrolytic cell uses a connected power source to conduct a nonspecific redox reaction. While galvanic cells have positive Ecell values, electrolytic cells are characterized by negative Ecell values.