2020 Mod 13 Flashcards

1
Q

In a chemical reaction, where is the potential energy? Where is the kinetic energy

A

The potential energy is in the bonds between the molecules

The kinetic energy is in the heat absorbed or released

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2
Q

If a chemical reaction is positive delta H Will the beaker containing the reaction feel hot or cold once the reaction is finished?

A

Cold

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3
Q

Why is Hesses law a more exact with the turn determining delta H then techniques that use bond energy’s

A

Has his law takes into account the different phases

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4
Q

What is a state function? Give two examples

A

A quantity that depends solely on the final destination not on the way got there

Enthalpy and Gibbs free energy are two examples

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5
Q

What substances will have a delta HF degree of zero?

A

Elements in their elemental form

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6
Q

If you have 2 50.0 KG block of copper And one temperature is 50° C wow the other temperature is 25° C which will have more entropy

A

The warmer one

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7
Q

If a chemical reaction is exothermic but has a negative S what could you do to the temperature to make it possible to re-run the reaction

A

Delta G equals delta H minus teetimes Delta S

Lower the temp to make T times Delta S smaller

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8
Q

What way will we think of energy and chemical reactions

A

When I chemical reaction is exothermic, energy will be thought of as a product in the reaction. If the reaction is endothermic, energy will be considered a reactant

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9
Q

Change in enthalpy delta H

A

The energy change that accompanies a chemical reaction

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10
Q

How many calories how many joules fit in one calorie

A

1 cal equals 4.184 Joules

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11
Q

When is Delta H positive and when is it negative

A

Delta H is positive for endothermic reactions, and delta H is negative for exothermic reactions

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12
Q

Endothermic

A

Delta H is positive heat is absorbed potential energy that is stored is greater than the reactants

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13
Q

Exothermic reactions

A

Delta H is negative heat is released the potential energy stored in the reactions products is less than the reactants

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14
Q

Is energy both absorbed and released during the course of a reaction

A

Yes

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15
Q

Equation 13.2

A

Delta H equals energy required to break bonds minus energy released when bond form

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16
Q

Hess’s law

A

Enthalpy is a state function

17
Q

State function

A

Eastate function is any quantity that depend solely on the final destinations not on the way it got to that destination

18
Q

Enthalpy of formation delta HF

A

The delta H of a formation reaction

19
Q

What is standard conditions

A

Room temperature 25°C

And 1.00 ATM

20
Q

What is the symbol of standard enthalpies of formation

A

Delta HF degrees

21
Q

Equation 13.3

A

Delta H degrees equals the sum of delta HF degrees product minus the sum of delta HF degrees reactant

22
Q

What is the standard entropy of the formation of an element in its elemental form

A

The standard enthalpy of formation of an element in it elemental form is zero

23
Q

What is an energy diagram

A

A picture of energy associated with a chemical reaction

24
Q

Activation energy

A

The energy necessary to start a chemical reaction

25
Q

Entropy

A

A measure of the disorder that exist in any system

26
Q

The second law of thermodynamics

A

The entropy of the universe must always either increase or remain the same I can never decrease

27
Q

What is the relative Entropy of the phases of matter

A

The solid state has the least amount of entropy associated with it. The entropy of the liquid state is higher in the entropy of the gaseous state is the highest of all

28
Q

How does entropy react with temperature

A

The entropy of a system increases with increasing temperature

29
Q

What problem exist in nature

A

The enthalpy of a system increases as the matter it contains increases

30
Q

Equation 13.4

A

Delta S universe is greater than or equal to zero

31
Q

Do all substances substances even elements have an absolute entropy

A

Yes

32
Q

Gibbs free energy

A

Delta G equals delta H minus tee times Delta S

33
Q

If delta H is less than zero

A

then the reaction is consistent with the second law and is spontaneous

34
Q

If delta G is greater than zero

A

then the reaction cannot proceed because it violates a second law