3.1.7 - Oxidation, reduction and redox equations Flashcards

1
Q

Define ‘oxidation’ in terms of

a) electrons
b) hydrogen
c) oxygen

A

Oxidation is

a) a loss of electrons from a species
b) a loss of hydrogen from a species
c) a gain of oxygen by a species

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2
Q

Define ‘reduction’ in terms of

a) electrons
b) hydrogen
c) oxygen

A

Oxidation is

a) a gain of electrons from a species
b) a gain of hydrogen from a species
c) a loss of oxygen by a species

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3
Q

Define the term ‘oxidising agent’

A

A substance that causes oxidation by being reduced itself

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4
Q

Define the term ‘reducing agent’

A

A substance that causes reduction by being oxidised itself

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5
Q

Oxidation state of hydrogen?

A

Usually: +1
Exception: with metal hydrides, hydrogen is -1

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6
Q

Oxidation state of group 1 metals?

A

Always +1

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7
Q

Oxidation state of group 2 metals?

A

Always +2

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8
Q

Oxidation state of aluminium?

A

Always +3

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9
Q

Oxidation state of oxygen?

A

Usually: -2
Exception: peroxides (H2O2) oxygen is -1; and in OF2, oxygen is +2

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10
Q

Oxidation state of fluorine?

A

Always -1

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11
Q

Oxidation state of chlorine?

A

Usually: -1
Exception:with fluorine or oxygen, chlorine is POSITIVE

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12
Q

Rule for assigning oxidation states?

A

The most electronegative element always has the negative value

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13
Q

What are the 4 most electronegative elements?

A

Chlorine < Nitrogen < Oxygen < Fluorine (most)

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14
Q

What does the oxidation state of an element in an IONIC compound tell you?

A

The number of electrons lost/gained by the ion compared to in its uncombined form

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15
Q

What does the oxidation state of an element in an MOLECULAR compound tell you?

A

The distribution of electron density between the atoms, due to differences in electronegativities (more electronegative means a negative oxidation state)

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16
Q

Oxidation state of uncombined elements?

A

Always ZERO!

17
Q

What does a half equation show?

A

Either oxidation or reduction

18
Q

How do you construct a half equation? x5

A

1 - Find the oxidation states of the species
2 - Balance the equation
3 - Balance OXYGEN with WATER
4 - Balance WATER with H+ IONS
5 - Balance CHARGES by adding ELECTRONS to one side

19
Q

How do you construct a full redox equation? x3

A

(By combining half equations)
1 - Multiply, so the number of electrons is equal on both sides
2 - Add each side (combine the half equations)
3 - Cancel electrons from each side

20
Q

What is a ‘disproportionation’ reaction?

A

One where atoms of the same element become both oxidised and reduced (into different products)