4.2.2 Haloalkanes Flashcards

1
Q

What are chloroethanes used for

A

Dry cleaning

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2
Q

What’s dichloromethane

A

A solvent in industry

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3
Q

What’s chloroform

A

An old fashioned anaesthetic

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4
Q

What have chlorofluorocarbons been used as in the past even though they’re now banned

A

Aerosol propellants + in fridges

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5
Q

What do chlorofluorocarbons damage

How

A

The ozone layer (O3)

When they decompose they produce very reactive Cl free radicals that destroy ozone molecules

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6
Q

What’s the ozone layer

A

Layer in atmosphere that absorbs UV radiation (chemical sunscreen)

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7
Q

3 factors of chlorofluorocarbons

A

Stable
Volatile
Non-flammable
Non-toxic

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8
Q

2 processes that generate Cl radical from chlorofluorocarbon

A

Homolytic fission

Initiation (UV light)

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9
Q

What does the greenhouse affect cause

A

The atmosphere to trap heat radiating from Earth towards space.

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10
Q

4 reasons global warming is a problem

A
  • sea levels rising causing flooding
  • rainfall less reliable
  • more droughts + heatwaves
  • hurricanes stronger and more intense
  • arctic ice melting
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11
Q

2 ways governments are working to limit global warming

A
  • reduce tropical deforestation
  • expand renewable energy use
  • increase vehicle fuel efficiency
  • place limits on amounts of emissions allowed
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12
Q

What’s the process called to break a polar bond

A

Heterolytic fission

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13
Q

What’s the d+ Carbon open to attack from in a polar bond

A

Nucleophiles (electron rich species)

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14
Q

Define nucleophile

A

Species that donates a lone pair of electrons

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15
Q

What is the mechanism type here

A

Nucleophilic substitution reactions of haloalkanes

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16
Q

What happens in nucleophilic substitution

A

The nucleophile approaches an organic molecule and takes the place of the halogen which then leaves

17
Q

What’s the conditions for nucleophilic substitution

A

Warm aqueous NaOH/KOH conditions

18
Q

What does reflux allow

A

Heating to boiling point without losing gases

19
Q

If conditions are warm + aqueous what will any metal hydroxide react with

A

Any halogenoalkane