Industrial Manufacturing Flashcards

1
Q

How is ammonia made

A

By combining nitrogen and hydrogen

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2
Q

Where is the hydrogen from

A

Natural gas or cracking of hydrocarbons

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3
Q

Where is the nitrogen from

A

From the air

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4
Q

Haber process equation

A

3H2(g) + N2 2NH3

^H = -92kJ/mol

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5
Q

Haber process conditions

A

450*C
200 atmospheres
Iron catalyst

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6
Q

Haber process

Why do the conditions not complete

A

Only some converted to ammonia
Gases cooked and ammonia turns to liquid
Unreacted goes back into the reaction chamber

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7
Q

Uses of ammonia

A

Manufacture of fertilisers
Manufacture of nitric acid
Manufacture of nylon

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8
Q

Making sulfuric acid is…?

A

The contact process

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9
Q

Making ammonia

A

The Haber process

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10
Q

Phase 1 contact process

A

Sulphur dioxide made by burning sulfur in air

S(s) + O2(g) -> SO2(g)

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11
Q

Phase 2 contact

A

2SO2(g) + O2 2SO3(g)

Temp of 450*
Pressure of 1-2atm
Vanadium oxide as catalyst
98%yield

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12
Q

Phase 3 contact

A

Sulfur trioxide combined with sulfuric acid
Weak due to impure
To make oleum

SO3(g) + H2SO4(l) -> H2S2O7(l)

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13
Q

Phase 4 contact

A

Oleum is diluted to make concentrated solution of sulfuric acid

H2S2O7(l) + H2O (l) ->2H2SO4(l)

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14
Q

Uses of sulfuric acid

A

Manufacture of detergents
Paints
Fertilisers

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15
Q

Manufacture of sodium hydroxide and chlorine

A

Electrolysis of sodium chloride (brine)

Hydrogen is the useful byproduct f electrolysis

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16
Q

Brine diagram key parts

A

Conc sodium chloride solution goes in

Titanium anode
Chloride out

Diaphragm

Steel cathode
Hydrogen out
Sodium hydroxide solution contaminated with sodium chloride out

17
Q

Brine anode

A

Titanium

2Cl- -> Cl2 + 2e-

Chloride ions lose electrons to form chlorine molecules

18
Q

Brine cathode

A

Steel

2H2O + 2e- -> 2OH- + H2

19
Q

Brine why keep apart

A

If they mix then they form bleach

20
Q

Uses of sodium hydroxide

A

Manufacture of bleach
Of paper
Of soup
Of detergents

21
Q

Uses of chlorine

A

Sterilising water supplies (swimming pools)
Manufacture of bleach
Of Hydrochloric acid
Of PVC