Alkali Metals Flashcards
What sort of solutions do alkali metals form when they react with water and what pH range is that solution?
They form alkaline solutions with a pH greater than 7 (8-14).
What are the group 1 metals (in order of reactivity?)
Lithium, Sodium, Potassium, Rubidium, Caesium and Francium
Why do alkali metals share similar characteristic chemical properties?
Alkali metals share similar characteristic chemical properties because they each have one electron in their outermost shell.
What are some properties of alkali metals?
They are soft (can be cut with a knife), knife, they have relatively low densities and low melting points and are very reactive (they only need to lose one electron to become highly stable).
What provides evidence for categorizing alkali metals into the same chemical family?
The reaction of the group 1 metals with water provides evidence for categorising these elements into the same chemical family.
What is the general word and chemical equation for alkali metals’ reaction with water? (Include state symbols)
group 1 metal + water ⟶ metal hydroxide + hydrogen
2M (s) + 2H2O (l) ⟶ 2MOH (aq) + H2 (g)
What are the common characteristics
across all of the hydroxides formed?
The common characteristic across all the hydroxides formed is that they all have the same general formula and are colourless, aqueous solutions.
Why are metals so named?
The metals are so named because they form alkalis in water.
What provides evidence of trends within group 1?
The differences between the reactions of the group 1 metals with water and oxygen provide evidence of trends within the group.
How do the reactions of alkali metals with water change as you descend the group?
The reactions of the alkali metals with water get more vigorous as you descend the group.
How does lithium react with water?
It is a relatively slow reaction, Lithium floats, fizzes, keeps its shape as it reacts and gets smaller and disappears. However, lithium does not melt.
How does Sodium react with water?
Floats, fizzes, melts into a ball (large amounts of heat is given off to melt the sodium), hydrogen released catches fire which causes the ball to dash around the surface and disappears leaving a white trail.
How does Potassium react with water?
Floats, fizzes, melts into a ball that dashes around the surface and enough heat is released so hydrogen burns with a lilac coloured flame
What do alkali metals form when they react with oxygen in the air?
The alkali metals react with oxygen in the air forming metal oxides.
Why do alkali metals tarnish when exposed to the air?
Alkali metals tarnish when exposed to air because they react with oxygen in the air forming metal oxides.
Describe the metal oxide produced/
The metal oxide produced is a dull coating which covers the surface of the metal.
What is the correlation
between the rate that the metal tarnishes and the position of the metal in the group?
The metal tarnish more rapidly as you go descend the group.
Describe the properties and physical trends in alkali metals
The alkali metals are soft and easy to cut (get softer as you move down the group), first three alkali metals are less dense than water (densities increases as you descend the group), all have relatively low melting points (decreases as you move down the group)
Why do melting points and boiling points decrease as you move down the group 1?
Melting and boiling points decrease as you move down the group, due to decreasing attractive forces between outer electrons and positive ions.
What are trends?
Trends are patterns of behaviour that change as you go down a group or across a period.
What can we say about Rb, Cs and Fr’s reactions with air and water in regards to the group 1 trends?
Following these trends, we can say that Rubidium, caesium and francium will react even more vigorously with air and water than the first three alkali metals.
Using the information given in the trends, what could we predict about rubidium?
Rubidium would be a soft grey solid, appear shiny when freshly cut, more dense than potassium and has a lower melting point than potassium.
When asked in the exam, what would be good words to make predictions about how rubidium would be expected to react with water?
Explosively and violently
How does reactivity change as you descend group 1?
The reactivity of the group 1 metals increases as you go down group 1.