Bonding And Molecular Architecture Flashcards

1
Q

Isoelectronic

A

Same electron configuration

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2
Q

Quantum numbers

A

N is the energy level
l is the orbital type
Ml is the orientations -1,0,1
Ms is direction of spin

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3
Q

Parent shapes for planar triangle

A

Trigonal planar
Bent
Linear

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4
Q

Shapes for tetrahedral

A

Tetrahedral
Trigonal pyramidal
Bent
Linear

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5
Q

Shapes for trigonal bipyramidal

A

Trigonal bipyramidal
Seesaw
T-shaped
Linear

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6
Q

Shapes for octahedral

A

Octahedral
Square pyramidal
Square planar

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7
Q

Hybrid orbital theory

A

Row 3
Sigma bonds
Pi bonds

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8
Q

Molecular polarity\bonding continuum

A
Use END 
3.3 ionic 
3.3-1.7 mostly ionic 
1.7-0.5 polar covalent 
0.5-0 slightly polar covalent 
0 nonpolar covalent
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9
Q

Intermolecular forces

A

Dispersion- momentary dipoles between all molecules through positive nucleus and e-
Dipole to dipole- polar molecules only, between the slightly - and + end
Hydrogen bonds- super strong dipole to dipole forces with FON
(Extra large negative end)

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10
Q
Covalent properties polar
Particles 
Force/bond
Boiling point
Electrical 
Hardness 
Soluble 
Electronegativities 
Ex
A
Polar molecules
Dipoles
Low intermediate 
Low
Soft
Soluble in polar 
Moderate ENDS 
Ice
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11
Q
Nonpolar covalent properties 
Particles 
Force/bond
Boiling point
Electrical 
Hardness 
Soluble 
Electronegativities 
Ex
A
Atoms or nonpolar 
Dispersions 
Lowest
Extremely low
Very soft
Soluble in nonpolar 
Similar 
Frozen oxygen long hydrocarbon chains
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12
Q
Ionic properties 
Particles 
Force/bond
Boiling point
Electrical 
Hardness 
Soluble 
Electronegativities 
Ex
A
Positive and negative ions 
Attraction between ions 
High
Only when melted
Hard and brittle
Polar solvents 
Widely different electro 
Table salt
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13
Q
Metallic properties 
Particles 
Force/bond
Boiling point
Electrical 
Hardness 
Soluble 
Electronegativities 
Ex
A
Sea of e- delocalized 
Metallic bond is string 
Intermediate to high 
Good 
Soft to hard, malleable and ductile
Molten metals 
Low electro 
Copper penny
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14
Q
Network covalent properties 
Particles 
Force/bond
Boiling point
Electrical 
Hardness 
Soluble 
Electronegativities 
Ex
A
Atoms
Covalent bonds strong
Highest
Doesn't conduct
Hardest things known
Insoluble 
Bond in four directions
Diamond
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15
Q

Order of boiling points lowest to highest

A
Molecule nonpolar- # of e- then shape 
Molecule polar- END
Molecule polar- # of H bonds 
Ionic- difference of ion charge then ENC
Network solids-
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16
Q

Boiling points of forces

A
Molecule nonpolar- dispersion
Molecule polar- dipole to dipole
Molecule polar- hydrogen bonds 
Ionic- ionic bonds 
Network solids