Carbonyls Flashcards
1
Q
Aldol reaction
A
Two carbonyl molecules joined by α-hydrogen extraction Between class II's
2
Q
Aldol condensation
A
An addition, then elimination to form an enone
Kicks off the alcohol by the addition of H+, forming a C=C double bond
Uses HCl/heat
3
Q
Claissen reaction
A
Forms β-carbonyl-carbonyl Attaches the carbonyl molecule to the carbon of the other carbonyl Carbonyls will be β to each other Uses MeOK Between class I's
4
Q
Decarboxylation
A
Must have carboxylic acid β to carbonyl
Ends with carbon dioxide and the carbonyl molecule minus the carboxylic acid.
5
Q
Enone
A
Two carbons double bonded with a double bond to oxygen on one
6
Q
Aldol addition
A
Takes off the alpha hydrogen leaving a negative alpha carbon, slaps the carbonyl molecule on the alpha carbon (double bond to oxygen breaks)
Ends with the original molecule attached to the other carbonyl, which now has an alcohol
Uses MeOK
Between class II’s