ch 1 Flashcards

1
Q

a sigma bond is

A

the overlap of 2 sp2 hybrid orbitals

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2
Q

A pie bond is

A

the overlap of 2 sp orbitals

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3
Q

a resonance structure

A

a molecule with mutable structures caused by moving electrons (the placement of the atoms stays the same but the e- move)

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4
Q

resonance structure rules

A
  1. atoms and single bonds stay the same
  2. Multiple bonds and lone pairs can change
  3. no braking octet rule
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5
Q

condensed notation rules:

A
  1. All atoms are written in but the bond lines are omitted
  2. Atoms are usually written next to the atoms they are bonded to
  3. () are used around similar groups bonded to the same atom
  4. Lone pairs are omitted
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6
Q

condensed notation rule exceptions (CHO)

A

notates a C that is double bonded to an O and a H (the O and H are not bonded)

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7
Q

skeletal structure rules

A
  1. Assume a Carbon atom is at the junction or end of a line
  2. each carbon must have enough Hydrogen atoms to give it 4 bonds
  3. Draw in anything different
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8
Q

neutral oxygen needs?

A

2 lone pairs and 2 bonds

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9
Q

Neutral Nitrogen needs?

A

1 lone pair and 3 bonds

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10
Q

Carbon is neutral with?

A

4 bonds

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11
Q

electron ownership: C (# valence e-)

A

4

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12
Q

electron ownership: C (+1 charge)

A

3 bonds around C

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13
Q

electron ownership: C (no charge)

A

4 bonds around C

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14
Q

electron ownership: C (-1 charge)

A

3 bonds and 2 lone e- around C

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15
Q

electron ownership: N (# valence e-)

A

5

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16
Q

electron ownership: N (+1 charge)

A

4 bonds around N

17
Q

electron ownership: N (no charge)

A

3 bonds and 2 lone e- around N

18
Q

electron ownership: N (-1 charge)

A

2 bonds and 4 lone e- around N

19
Q

electron ownership: O (# valence e-)

A

6

20
Q

electron ownership: O (+1 charge)

A

3 bonds 2 lone e-

21
Q

electron ownership: O (no charge)

A

2 bonds 4 lone e-

22
Q

electron ownership: O (-1 charge)

A

one bond 6 lone e-

23
Q

hybrid orbitals: 2 groups (how many orbitals)

A

2 orbitals

24
Q

hybrid orbitals: 2 groups (type of orbitals)

A

2 sp orbitals

25
Q

hybrid orbitals: 2 groups (bonding angle)

A

180 degrees

26
Q

hybrid orbitals: 3 groups (# or orbitals)

A

3

27
Q

hybrid orbitals: 3 groups (type)

A

3 sp2 orbitals

28
Q

hybrid orbitals: 3 groups (angle)

A

120 degrees

29
Q

hybrid orbitals: 4 groups (# of orbitals)

A

4

30
Q

hybrid orbitals: 4 groups (type of orbitals)

A

4 sp3 orbitals

31
Q

hybrid orbitals: 4 groups (angle)

A

109.5 degrees