Chapter 10 Salts Flashcards

1
Q

Acid+ metal=

A

salt+hydrogen

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2
Q

Acid+ base/alkali

A

salt+ water (neutralisation)

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3
Q

Acid+ carbonate

A

salt+ water+ carbon dioxide

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4
Q

Nitric acid chemical formula

A

HNO3

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5
Q

Hydrochloric acid chemical formula

A

HCl

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6
Q

Sulfuric acid chemical formula

A

H2SO4

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7
Q

What does solubility mean?

A

Solubility refers to the maximum amount of substance that can be dissolved in a given volume of solvent (usually water).

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8
Q

Which nitrates are soluble?

A

All nitrates are soluble

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9
Q

Which chlorides are insoluble?

A

Lead(II) chloride, PbCl2
Silver chloride, AgCl

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10
Q

Which sulfates are insoluble?

A

Calcium sulfate, CaSO4
Lead(II) sulfate, PbSO4
Barium Sulfate, BaSO4

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11
Q

Which carbonates are soluble?

A

Sodium carbonate, Na2Co3
Potassium carbonate, K2Co3
Ammonium carbonate, (NH4)2CO3

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12
Q

How to prepare non-SPA salts?

A

-By adding excess metal, metal oxide, metal hydroxide or metal carbonate to acid
-acid+ insoluble = soluble salt

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13
Q

How to prepare zinc sulfate?

A
  1. Add excess zinc powder until no more zinc dissolves or no more effervescence (H2) is observed.
  2. Filter to remove the excess (unreacted) zinc and obtain zinc sulfate solution as filtrate.
  3. Heat the filtrate to obtain a saturated solution. Leave the solution to cool and crytallise.
  4. Filter the mixture to obtain zinc sulfate crystals as residue.
  5. Rinse the crystal with a little distilled water and dry between sheets of filter paper
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14
Q

What is titration use for?

A

-SPA salts can be prepared by adding an alkali or SPA carbonate to acid
-acid + soluble = soluble salt

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15
Q

How to find the exact volume of acid for exact reaction?

A
  1. Pipette 25.0 cm3 of sodium hydroxide into a conical flask
  2. Add a few drops of indicator into the flask
  3. Add dilute nitric acid slowly from the burette until the solution changes colour permanently
  4. Note the volume of acid added
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16
Q

Salt preparation for titration steps

A
  1. Repeat the titration without adding the indicator and add the same volume of acid to 25.0cm3 of sodium hydroxide to obtain the salt solution
  2. Heat the solution to evaporate the water and obtain a saturated solution
  3. Leave the saturated solution to cool so that crystals can form
  4. Filter to obtain sodium nitrate crystals as residue
  5. Rinse the crystals with a little cold distilled water to remove water-soluble impurities and dry between sheets of filter papers
17
Q

Why cannot add indicator on second titration?

A

It will make the salt impure.

18
Q

What is precipitation use for?

A

-Insoluble salts can be prepared by adding two solutions together.
-soluble + soluble = insoluble salt

19
Q

Preparation of Lead(II) sulfate

A
  1. Add excess sodium sulfate to lead(II) nitrate and stir until no more precipitate forms
  2. Filter the mixture to obtain lead(II) sulfate as residue
  3. Rinse the precipitate with distilled water to remove water-soluble impurities
  4. Dry the precipitate between sheets of filter paper
20
Q

Preparation of Lead(II) sulfate

A
  1. Add excess sodium sulfate to lead(II) nitrate and stir until no more precipitate forms
  2. Filter the mixture to obtain lead(II) sulfate as residue
  3. Rinse the precipitate with distilled water to remove water-soluble impurities
  4. Dry the precipitate between sheets of filter paper