Chapter 16: Carbohydrates Flashcards
Upon monosaccharide cyclization, the carbon that becomes chiral is referred to the …
anomeric carbon
Monosaccharides that differ only in the configuration at the anomeric carbon are called …
anomers
murarotation
interconversion of the a- and b-forms of monosaccharides
An alcohol and an anomeric carbon of a monosaccharide produces an acetal bond called…
O-glycosidic bond
These consist of 2 monosaccharides covalently attached via a glycosidic bond
disaccharides
Name some common dissacharides
maltose trehalose sucrose cellobiose lactose gentiobiose
What are homopolysaccharides?
aka homoglycans
polysaccharides containing only one kind of monosaccharide
What are heteropolysaccharides?
aka heteroglycans
polysaccharide containing more than one kind of monosaccharide
Starch is the main storage homopolysaccharide in (animals/plants).
plants
Starch is a mixture of two homopolysaccharides of glucose, which are..
amylose
amylopectin
-branched homopolysaccharide of glucose
-branch-points with (a1 -> 6) linkers every 8-12 residues
-molecular weight reaches several millions
functions as the main storage polysaccharide in animals
glycogen
most abundant natural polymer in the world
-linear polymer of D-glucose units linked by a (b1 -> 4) linked residues
cellulose