Chapter 16: Carbohydrates Flashcards

1
Q

Upon monosaccharide cyclization, the carbon that becomes chiral is referred to the …

A

anomeric carbon

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2
Q

Monosaccharides that differ only in the configuration at the anomeric carbon are called …

A

anomers

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3
Q

murarotation

A

interconversion of the a- and b-forms of monosaccharides

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4
Q

An alcohol and an anomeric carbon of a monosaccharide produces an acetal bond called…

A

O-glycosidic bond

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5
Q

These consist of 2 monosaccharides covalently attached via a glycosidic bond

A

disaccharides

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6
Q

Name some common dissacharides

A
maltose
trehalose
sucrose
cellobiose
lactose
gentiobiose
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7
Q

What are homopolysaccharides?

aka homoglycans

A

polysaccharides containing only one kind of monosaccharide

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8
Q

What are heteropolysaccharides?

aka heteroglycans

A

polysaccharide containing more than one kind of monosaccharide

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9
Q

Starch is the main storage homopolysaccharide in (animals/plants).

A

plants

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10
Q

Starch is a mixture of two homopolysaccharides of glucose, which are..

A

amylose

amylopectin

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11
Q

-branched homopolysaccharide of glucose
-branch-points with (a1 -> 6) linkers every 8-12 residues
-molecular weight reaches several millions
functions as the main storage polysaccharide in animals

A

glycogen

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12
Q

most abundant natural polymer in the world

-linear polymer of D-glucose units linked by a (b1 -> 4) linked residues

A

cellulose

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