Chemical Bonding Flashcards

1
Q

Ionic

A

complete transfer of 1 or more electrons from one atom to

another

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2
Q

Covalent

A

some valence electrons shared between atoms

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3
Q

polar covalent

A

somewhere in between ionic and covalent

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4
Q

why do elements form compounds

A

to “hold” a full outer (valence shell) of electrons…….Octet rule

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5
Q

Valence electrons are …… …… …….. Core e are ///

A

involved in bonding, not

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6
Q

covalent bonding arises from….

A

the mutual attraction of 2 nuclei for the

same electrons

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7
Q

valence electrons are in

A

the outer shell.

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8
Q

Due to the bond polarity the H–Cl bond energy is…..

A

is GREATER than expected for a “pure” covalent bond

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9
Q

electronegativity

A

a measure of the ability of an atom in a molecule to attract electrons to itself

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10
Q

the diff between pure bond energy and real bond energy is prop to

A

electronegativity

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11
Q

which bond is more polar? o—h or o—f

A

oh

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12
Q

polar or..

A

dipolar

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13
Q

the relative attraction an atom in a molecule has for the share pair of electrons in a covalent bond

A

electronegativity

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14
Q

higher electro negative difference means

A

high electric field across the molecule.

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15
Q

even if bonds are polar, some molecules are not polar …

A

the symmetry cancels it.

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16
Q

is CO2 a polar molecules?

A

no.

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17
Q

is methane polar?

A

no

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18
Q

single bond

A

can rotate easily

19
Q

double bond

A

cant rotate.

20
Q

bond length

A

is the distance between nuclei of two bonded atoms

21
Q

bond order

A

the number of bonds between pairs of atoms

22
Q

bond order prop to

A

bond strength& length

23
Q

bong length depends on

A

size of bonded atoms

24
Q

bond strength

A

the energy required to break a bond

25
Q

bond strength increase as bond order

A

increases

26
Q

resonance structure the bond order is

A

non whole number

27
Q

breaking bonds

A

requires energy(endo)

28
Q

bonds formed

A

releases energy(exo)

29
Q

intramolecular

A

covalent, ionic

30
Q

intermolecular bonding

A

van der waals, hydrogen, dipole dipole

31
Q

ion dipole forces-e.g NA+ in sodium chloride molecule attracting o- in h20

A

attraction between ions and permanent dipoles

32
Q

hydrated ions

A

water can interact with + ions to give these

33
Q

dipole dipole forces

A

bind molecules that have permanent dipoles to one another

34
Q

influence of di-di forces is seen in

A

boiling points

35
Q

hydrogen bonding:

attraction between a /// pair on one ////// and a hydrogen atom attached to an ////-element on another

A

..

36
Q

h bonding is strongest with

A

O, N, F

37
Q

Why N,O, AND F?

A

they are the most electro- elements on table.

38
Q

the hydrogen bonding in water is very strong

A

there are two lone pairs of e- around o and two h on each.

39
Q

how does o2(non polar) and i2 dissolve in water

A

water INDUCES dipole in o2 etc

40
Q

polarisation

A

inducing a dipole

41
Q

polarisibilty of a molecule

A

degree to which e- cloud of a molecule can be distorted

42
Q

larger molecules

A

> larger induced dipoles»>larger boiling points

43
Q

boiling point is a ….. of the ……. of ……… forces

A

meausre, strength, intermolecular

44
Q

………forces are in non …..molecules

A

induced, polar