chemical change (electrolysis) (paper 1) Flashcards

1
Q

electrolysis

A

when an ionic compound splits into its elements using electricity

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2
Q

do solid ionic compounds conduct electricity

A

no because the ions are fixed

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3
Q

do molten ionic compounds and ionic compounds in a solution conduct electricty

A

yes because the ions are free to move

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4
Q

what is the ionic compound you need to separate called

A

the electrolyte

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5
Q

what are the electrodes made from

A

an inert (un reactive) substance eg graphite or platinum

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6
Q

how many ions are in the beaker during electrolysis of a molten compound

A

2

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7
Q

explain the steps of electrolysis of a molten compound

A
  1. the positive ion moves to the negative electrode because opposites attract
  2. the negative ion moves to the positive electrode because opposites attract
  3. _____ ion gains an electron to become a _____ atom. this is reduction
  4. then say what substance is made at the electrode
  5. ____ ion loses an electron to become a ____ atom. this is oxidation
  6. then say what is made at the positive electrode
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8
Q

electrolysis of motlen aluminium oxide

A

molten aluminium oxide seperates into aluminium and oxygen

oxygen will move to the positive electrode because opposites attract

aluminium will move to the negative electrode because opposites attract

oxygen is made at the positive electrode

aluminium is made at the negative electrode

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9
Q

the problems with aluminium oxide

A

the oxygen reacts with the carbon electrode to make carbon dioxide which wears the positive electrode away and then it needs replacing

for electrolysis aluminium oxide has to be heated to 2500 degrees , this needs a lot of energy and costs a lot of money

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10
Q

what is cryolite

A

a substance that gets mixed with aluminium oxide which lowers the melting point to 800 degrees so it needs less energy and costs them less money

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11
Q

in electrolysis of solution how many ions are in the beaker

A

4

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12
Q

what ions do water molecules seperate
into

A

H+

OH-

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13
Q

rules for ionic solutions at the anode

A

if the ions are halogens , the HALOGEN is made

if the ions are NOT halogens , oxygen is produced

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14
Q

rules for ionic solutions at the cathode

A

if the ions are MORE REACTIVE than hydrogen , then HYDROGEN is produced

if the ions are less reactive than hydrogen , the METAL is produced

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15
Q

in a chemical cell what is the size of the voltage determined by

A

concentration of electrolyte

temperature of electrolyte

type of electrolyte

type of electrode

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16
Q

what does the bigger difference in reactivity between the two metals do in a chemical cell

A

the more reactive = more voltage

17
Q

what is the voltage like of electrodes of the same material in a chemical cell

A

there is no voltage produced

18
Q

why can rechargeable batteries be recharged

A

the reaction used in the cell is reversible

the reaction will reverse when an electric current is applied

19
Q

why can non rechargeable batteries not be recharged

A

the reaction used in the cell is irreversible

the reaction will stop when one of the reactants has been used up

20
Q

what are fuel cells

A

a fuel (eg hydrogen) is constantly supplied with a supply of oxygen

the hydrogen is oxidised to make water

equation : 2H2 +O2 ——> 2H2O

21
Q

how do fuel cells work

A

hydrogen and oxygen are pumped into the fuel cell

the hydrogen atom lose electrons to become hydrogen ions and flow through the barrier

the electrons move around the circuit which generates a current

at the anode the electrons join with oxygen and hydrogen ions to produce water

22
Q

advantages of using hydrogen fuel cells over rechargeable cells

A

faster to refuel than recharging

lasts longer

hydrogen can be renewable

produces a constant voltage

no carbon dioxide given off

23
Q

disadvantages of using hydrogen fuel cells over rechargeable cells

A

hydrogen is made form fossil fuels

hydrogen is made from non renewable resources

hydrogen is difficult to store

24
Q

how many ions are there in an aqueous solution during electrolysis

A

4

25
Q

what ions are there always in an aqueous solution during electrolysis

A

H+ and OH-

26
Q

what is the test for chlorine gas

A

bleaches damp litmus paper, turning it white