CHEMICAL TESTS Flashcards

1
Q

Sulphate ions (SO4 2-)

A

1) acidify with HCl
2) add BaCl

Positive - white precipitate (BaSO4)

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2
Q

Test for Carbonate ions (CO3 2-)

A

Add dilute HCl

Effervescence - gas produced

Turns lime water cloudy

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3
Q

Hydroxide ions (OH-)

A

1) damp RED litmus paper

Positive turns red to blue

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4
Q

Halide Cl-

A

1) acidify with HNO3 (not HCl due to Cl- ion present in acid!)
2) add AgNO3 - silver nitrate solution
3) add dilute NH3 then conc. NH3 (to double check)

Positive = white ppt
Also dissolves in the dilute ammonia!

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5
Q

Halide Br-

A

1) acidify with HNO3 (not HCl due to Cl- ion present in acid!)
2) add AgNO3 - silver nitrate solution
3) add dilute NH3 then conc. NH3 (to double check)

Positive = cream ppt
Only dissolves in CONC NH3

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6
Q

Halide I-

A

1) acidify with HNO3 (not HCl due to Cl- ion present in acid!)
2) add AgNO3 - silver nitrate solution
3) add dilute NH3 then conc. NH3 (to double check)

Positive = yellow ppt and insolvable in ammonia

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7
Q

Mg2+

A

Add NaOH - white ppt

Ass H2SO4 - no change

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8
Q

Ca2+

A

Brick red flame test

with dilute NaOH - white ppt

With dilute H2SO4 - slight white ppt

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9
Q

Sr2+

A

Red flame test

with dilute NaOH - no change

With dilute H2SO4 - white ppt

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10
Q

Ba2+

A

Green flame test
- add dilute NaOH - no change

  • dilute H2SO4 - white ppt
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11
Q

NH4+

A

1) add NaOH
2) heat
3) hold damp red litmus paper at test tube mouth - litmus paper turns from red to blue

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12
Q

Cl2 test

A

Bleaches damp litmus paper

H2O + Cl2 —> HCl + HOCl

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13
Q

H2 (gas)

A
  • pops with lit splint
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14
Q

Oxygen

A

Relights glowing splint

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15
Q

Al3+ test

A

Add aqueous NaOH

White Ppt dissolves in XS

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16
Q

Any acid or H+ ions

A

1) turns blue litmus paper red
Or
Effervescence with sodium carbonate

17
Q

Unsaturated Hydrocarbons (C=C)

A

Decolourise bromine water

18
Q

Aldehydes

A
  • tollens reagent ([Ag(NH3)2]+
    Forms silver mirror
  • fehling’s solution - blue coloured —> brick red ppt
19
Q

Carboxylic acids

A

Release CO2 when shaken with sodium Carbonate

20
Q

Test for acyl chloride

A

Gives misty fumes with water

21
Q

Test for alcohol

A

Acidified potassium dichromate (K2Cr2O7)

Orange to green