Electrochemical Cells And Electrode Potentials Flashcards

1
Q

What’s oxidation and reduction

A

Oxidation- loss of electrons
Reduction- gain of electrons

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2
Q

What reaction occur when Fe^/Fe half cell is joined to the Mg^/Mg half cell

A

X more positive E* so X will be reduced and Y will be oxidised

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3
Q

Why does a reaction occur

A

E* of X/ is more positive than E* of Y/Y

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4
Q

When can a molecule of D oxidise E / another molecule of itself

A

When the E* value of D > E* value of E

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5
Q

How do you identify the weakest oxidising agent

A

Species on the LHS with the most negative E* value

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6
Q

What are the essential properties of the separator

A

Non reactive
Porous
Allow ions to cross

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7
Q

What is the function of the carbon rod in a non rechargeable cell

A

Allows electrons to flow

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8
Q

Why might a non rechargeable cell leak after being used for a long time

A

Zinc is used up during the process

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9
Q

Why is ethanol considered a carbon fuel

A

CO2 released by combustion and fermentation is equal to that taken up in photosynthesis

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10
Q

Why are electrodes made by coating ceramic material than using actual rods (not cost)

A

Increase surface area

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11
Q

Suggest why the emf value of hydrogen octogenarian fuel cell operating in acidic conditions is exactly the same as that of the alkaline cell

A

Same overall equation

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12
Q

Suggest one reason why the cells can’t be electrically recharged

A

Reactions not reversible

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13
Q

Give one reason why the emf of the lead acid cell changes after several hours

A

Reagents are used up

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14
Q

Explain why voltage remains constant in the fuel cell

A

Conagsnt supply of fuel and oxygen

Concentration remain constant

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15
Q

Main advantage of fuel cell for electric cars apart from pollution

A

Hydrogen ant oxygen supplied continuously can be operated without stopping to recharge

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