Energetics Flashcards

1
Q

Definition of Enthalpy Change

A

The heat energy transferred in a reaction at constant pressure

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2
Q

The Standard Conditions for Enthalpy Change -o-

A

100 kPa (1 atm) and a stated temperature

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3
Q

The value of the Enthalpy Change for an Exothermic Reaction

A

-

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4
Q

The value of the Enthalpy Change for an Endothermic Reaction

A

+

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5
Q

Definition of Bond Enthalpy

A

The energy needed to break a bond

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6
Q

What happens when you break bonds

A

Energy is needed to break the bond, so it is endothermic and +

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7
Q

What happens when you make bonds

A

Energy is released, so it is exothermic and -

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8
Q

Definition of mean Bond Enthalpy

A

The average energy needed to break a certain type of bond over a range of compounds

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9
Q

Equation for calculating Enthalpy Change

A

Enthalpy change of reaction = total energy absorbed - total energy released

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10
Q

Definition of Standard enthalpy change of Formation

A

the enthalpy change when 1 mole of compound is formed from its elements in their standard states under standard conditions

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11
Q

Definition of Standard enthalpy change of Combustion

A

the enthalpy change when 1 mole of compound is completely burned in oxygen with all reactants and products in their standard states under standard conditions

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12
Q

Definition of Standard enthalpy change of Reaction

A

the enthalpy change when a reaction occurs in the molar quantities shown in the chemical equation under standard conditions with all reactants and products in their standard states

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13
Q

Description of the measuring enthalpy change practical

A
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14
Q

The Equation for

A

q = mc(delta)T

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15
Q

How to measure an enthalpy of neutralisation

A
  1. add a known volume of acid into an insulated container and measure the temperature
  2. add a known volume of alkali and record the temperature at intervals, stir to make sure it is evenly heated
  3. work out temperature change and then work out the energy given out using q = mc(delta)T
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16
Q

Definition of Enthalpy of Neutralisation

A

The energy change when 1 mole of water is formed by the reaction of an acid and an alkali

17
Q

Definition of Hess’ Law

A

The total enthalpy change for a reaction is independent of the route taken

18
Q

How to draw a Hess Cycle for enthalpy of formation

A
  1. Write out the reaction
  2. write the elements in their standard states below the reaction
  3. draw arrow upwards to reactants and products
19
Q

How to draw a Hess Cycle for enthalpy of combustion

A
  1. Write out the reaction
  2. write the elements as combustion products
  3. draw arrow downwards from reactants and products