Equilibrium ii (11) Flashcards
The only factor that affects the eq. constant
Temperature
What are the units for Kc?
Must be worked out using the concentrations. Each species being in Moldm-3
What is NEVER included in Kc expression?
Solids
Partial pressure=
Mole fraction * total pressure
Mole fraction of species x =
No. moles of species x / total No. moles of all species
Kp units
KPa for each species
But must be worked out each time
Kp=
p(C)p(D) / p(A)p(B)
p=partial pressure
If you half the volume of a container, what happens to pressure of the system?
Doubles
Effects of temperature equation
RlnK=delta S system + (-delta H) / T
All exothermic reactions have what delta H
Negative
Making (-delta H / T) positive as - - = +
All endothermic reactions have what delta H ?
Positive
So (-delta H / T) is negative as + - = -
Effects of T summary: Exothermic
Increasing T = lower K
Decreasing T = higher K
Effects of T summary: Endothermic
Increasing T = higher K
Decreasing T = lower K