Exam 4 Flashcards

1
Q

does a cation that’s part of a strong base affect the pH?

A

nah

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2
Q

common-ion effect

A

shift in position of equilibrium caused by the addition of an ion

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3
Q

the lower the pKa…

A

the higher the pH

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4
Q

pH buffer

A

solution of a weak acid and its conjugate base that is resistant to pH changes

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5
Q

buffer range

A

pH range within which a given buffer can provide ph protection

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6
Q

to make a buffer:

A

1) pick acid whose pKa is the pH you want +-1

2) determine the base to acid ratio you need to get the target pH

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7
Q

buffer capacity

A

quantity of acid/base that a buffer can neutralize while maintaining pH within desired range

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8
Q

pH indicators

A

water-soluble and weak organic acids that change color as the pH changes

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9
Q

what’s a buffer solution usually made up of?

A

weak acid and its conjugate base

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10
Q

decrease in H+ does what to the pH?

A

raises it (shifts reaction to the left)

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11
Q

when can you apply the common-ion affect?

A

any equilibrium involving a weak acid and its conjugate base

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12
Q

pKb+pKa=

A

14

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13
Q

equivalence point

A

equal # of moles of acid and base

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14
Q

alkalinity titration

A

buffer capacity of a solution against addition of acid

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15
Q

why is an alkalinity titration more complex?

A

it has 2 equivalence points

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16
Q

pH at equivalence point in the titration of a weak acid with a strong base?

A

> 7

17
Q

Ksp

A

solubility product

18
Q

molar solubility

A

amount of dissolved solute expressed as mol/L

19
Q

molar solubility symbol

A

S

20
Q

higher solubility when

A

at higher temp

21
Q

solubility product constant

A

Ksp

22
Q

1/2 way to the equivalence point, what does the pH equal?

A

the pKa

23
Q

what is solubility measured in?

A

g/L or mg/L

24
Q

when is the solubility higher?

A

at a higher temp

25
Q

for insoluble salts that contain basic anions, what happens to the solubility as the pH decreases?

A

solubility increases

26
Q

Q>K

A

precipitate forms

27
Q

Q < K

A

dissolves (no precipitate)

28
Q

the lower the pKa value…

A

the stronger the acid