Exam I: Lipidy Stuff Flashcards
Why is the term amphipathic this used to describe lipids? Why is it important?
Because they have a hydrophilic segment and a hydrophobic tail. It allows then to function as barriers in the watery environment if our bodies.
What is the common property of lipids?
They are water insoluble long chain hydrocarbons with a terminal carboxyl group.
What are the major classes of lipids?
- Glycerolipids
- Phospholipids
- Sphingolipids
What types of structures fall into the category of Glycerolipids?
- Triglycerols/triglycerides
- Glycerophospholipids
- Ether glycerolipids
What structures fall into the category of phospholipids?
- Glycerophospholipids
- Ether Glycerolipids
- Sphingophospholipids
What structures fall into the category of sphingolipids?
- Sphingophospholipids
2. Glycolipids
What are important characteristics of triglycerides (5 things)
- How FA’s are stored
- They are esters of glycerol and FA’s
- A concentrated form of energy
- Less dense than water
- Don’t cause osmotic problems in body (particularly hydrophobic)
Describe structure and purposes of phospholipids.
- Like triglycerides, but replace one FA with with a phosphate headgroup (hydrophilic!)(amphipathic!)
- Some are esters of glycerol-3-phosphate and FA’s
- component of CELL MEMBRANE
Describe structure and purposes of sphingolipids.
- Another type if membrane lipid.
- Have sphingosine backbone
- Sphingomyelins are phospholipids.
- 2 types: either with a carb group or a phosphate head group.
(NANA?)
What is a fatty acid?
Also: triglycerides.
Water insoluble long-chain hydrocarbons with a terminal carboxyl group .
What is the difference between a mono-unsaturated and poly-unsaturated fatty acid?
Mono-unsaturated: one double bond
Poly- unsaturated: more than one double bond
What is the configuration of the double bond in most naturally occurring unsaturated fatty acids?
Cis
What is the relationship of the fatty acid chain length to membrane fluidity and melting point??
As chain gets longer, melting point goes up. (More bonds to break)
As chain gets longer, membrane gets LESS fluid.
Relationship of degree of FA unsaturation to membrane fluidity and to melting point?
The less saturated, the lower the melting point (don’t pack well)
More fluid than saturated FA’s
Which end does the delta naming count carbons from? Omega?
The carboxyl end. The methyl end.