Extraction of Metals Flashcards
Why is roasting necessary?
Sulphide ores cannot be converted directly into the metal. Instead they must be converted to the oxide.
Equations of production of SO2 from Pb and Zn ore
2ZnS + 3O2(g) 2ZnO(s) + 2SO2(g)
2PbS + 3O2(g) 2PbO(s) + 2SO2(g)
Why does roasting cause problems?
Acid rain but if the sulphur dioxide can be collected before being released into the atmosphere, it can be used to make sulphuric acid.
Outline the extraction of Iron
- Heating the furnace
The coke reacts with the oxygen at the base of the furnace to produce carbon dioxide. This is an exothermic reaction and keeps the furnace hot:
C(s) + O2(g) -> CO2(g)
- Making the reducing agent
The carbon dioxide rises up the furnace and reacts with more coke to produce carbon monoxide. This is an endothermic reaction:
C(s) + CO2(g) -> 2CO(g)
- Reducing the iron oxide
The carbon monoxide is a reducing agent and reduces the haematite to iron:
Fe2O3(s) + 3CO(g) -> 2Fe(l) + 3CO2(g)
The liquid iron sinks to the base of the furnace and is tapped off.
Some of the haematite is reduced directly by the carbon:
Fe2O3(s) + 3C(s) -> 2Fe(s) + 3CO(g)
Outline the extraction of manganese and copper
Blast furnace
MnO2(s) + 2CO -> Mn(l) + 2CO2(g)
MnO2(s) + 2C(s) -> Mn(l) + 2CO(g)
CuO(s) + CO(g) -> Cu(l) + CO2(g)
CuO(s) + C(g) -> Cu(l) + CO(g)
Advantages of using a blast furnace
- the raw materials are very cheap
- the reaction is exothermic, so less energy is needed to keep the furnace hot
- the purity of the iron is sufficient for most steel-making purposes
- it is a continuous process which means iron can be made more efficiently
Disadvantages of using a blast furnace
- the use of carbon does mean carbon dioxide is released (it is a greenhouse gas)
- metals which are higher than carbon in the reactivity series (eg aluminium) cannot be extracted in this way
- metals which react with carbon to form carbides (eg titanium and tungsten) cannot be extracted in this way
- metals that need to be very pure cannot be produced in this way, as the metal produced always contains significant quantities of carbon
Outline the extraction of aluminium
Once the bauxite has been purified, electrolysis can start.
Al2O3 has a melting point of 2000oC, which is too high to enable it to be electrolysed feasibly. It is thus dissolved in molten cryolite, Na3AlF6, and the solution is electrolysed at 900oC.
Oxygen is liberated at the anode, which is made of graphite:
2O2- -> O2(g) + 4e
Aluminium is liberated at the cathode, which is also made of graphite:
Al3+ + 3e -> Al(l)
The overall cell reaction is thus as follows:
2Al2O3 -> 4Al(l) + 3O2(g)
Advantages of electrolysis
- It is a continuous process, so is efficient
2. It makes the metal in pure form
Disadvantages of electrolysis
- The cost of melting the aluminium and supplying the energy for electrolysis is very high
- It only works for ionic oxides
Why isn’t coke used for tungsten and titanium?
In many cases, carbon cannot be used to reduce the metal oxide to the metal as the metal reacts with carbon to form the carbide instead. This is the case with tungsten and titanium:
TiO2(s) + 3C(s) -> TiC(s) + 2CO(g)
2WO3(s) + 9C(s) -> W2C3(s) + 6CO(g)
Why is titanium ore first converted to a chloride?
Magnesium forms an alloy with the titanium
Outline the extraction of Titanium
- Conversion of ore into chloride
TiO2 is heated in a stream of chlorine, in the presence of coke, to produce TiCl4.
TiO2(s) + 2C(s) + 2Cl2(g) -> TiCl4(g) + 2CO(g)
The TiCl4 is covalent and volatile. It can be separated from the other products by fractional distillation.
- Reduction of the chloride
The Ti is extracted from its chloride by reduction with magnesium or sodium:
TiCl4(g) + 2Mg(l) -> Ti(s) + 2MgCl2(l)
TiCl4(g) + 4Na(l) -> Ti(s) + 4NaCl(l)
These reactions are exothermic and keep the reaction vessel at a very high temperature.
This process is known as the Kroll process. An inert atmosphere of argon is used to prevent the magnesium or sodium reacting with oxygen.
Advantage of extraction of Titanium
It produces very pure titanium
Disadvantages of extraction of Titanium
- It is a batch process, which means the titanium is not produced continuously. This adds to the cost of the process.
- The sodium/magnesium are expensive
- The energy costs are very high