fea p1,2 Flashcards

1
Q

what does Avogadro’s constant represent?

A

the number of atoms per mole of the carbon-12 isotope

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2
Q

how do you calculate the mass of 1 mole of an element?

A

mass of 1 mole = relative atomic mass in grams

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3
Q

equation linking moles, mass and mr?

A

moles (mol) = mass (g) / molar mass (g mol-1)

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4
Q

what is an empirical formula?

A

simplest whole number ratio of atoms of each element present in a compound

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5
Q

how do you calculate empirical formula?

A

set mass to percentage, vice versa (must add to 100)
divide the amount of each element by its mr
divide the answers by the smallest value obtained
ratio!

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6
Q

what is Avogadro’s law?

A

under the same temperature and pressure, one mole of any gas would occupy the same volume

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7
Q

how much volume does a gas occupy at room temp and pressure?

A

24 dm3 or 24000 cm3

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8
Q

molar gas volume

A

the volume per mole of gas molecules

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9
Q

why do different gas particles occupy the same volume?

A

the gas particles are very spread out, hence the individual differences has no effect

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10
Q

how do you calculate moles when gas volume is given?

A

moles = volume (dm3) / 24
moles = volume (cm3) / 24000

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11
Q

what are the ideal ways in which gases behave?

A

continuous motion
no intermolecular forces experienced
exert pressure when they collide with each other or container
no kinetic energy lost in collisions
when temp increases, kinetic energy of gases increase

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12
Q

ideal gas equation and units

A

pV = nRT
pressure (Pa)
volume (m3)
temperature (K)

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13
Q

1 atm = ? Pa

A

1 atm = 101325 Pa

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14
Q

how do you convert from *C to K?

A

+ 273

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15
Q

what does concentration of a solution mean?

A

amount of solute dissolved in 1 dm3 of solvent

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16
Q

equation linking moles, conc and volume

A

moles = concentration (moles dm-3) x volume (dm3)

17
Q

what is a standard solution?

A

a solution of known concentration

18
Q

how do you prepare a standard solution?

A

1 weigh solute using weigh by difference method
2 dissolve solute in beaker using the solvent
3 pour solution into volumetric flask
4 rinse the beaker using the solution (e.g. distilled water) and add to flask
5 add solvent to flask until it reaches graduation line
6 mix solution thoroughly

19
Q

concentrated
dilute

A

concentrated - large amount of solute per dm3 of solvent
dilute - small amount of solute per dm3 of solvent

20
Q

percentage yield definition

A

efficiency of which reactants are converted into products

21
Q

why might the percentage yield not be 100%?

A

reaction may be at equilibrium
reactants may be impure
side reactions could happen
reactants or products may be left behind when transferring
loss of products during separation and purification

22
Q

percentage yield equation

A

percentage yield = actual amount of product (mol) / theoretical amount of product (mol) x 100

23
Q

atom economy?

A

proportion of desired products compared with all the products formed in the reaction

24
Q

atom economy equation?

A

atom economy = mr of desired product / sum of the mr of all products x 100

25
Q

does 100% yield = 100% atom economy?

A

no, even if all the reactants are converted into products, not all products of the reaction will be required products

26
Q

what type of reaction has 100% atom economy?

A

addition reactions (two or more reactants combined to form one product)

27
Q

systematic error

A

same error appears in each measurement

28
Q

what is the weighing by difference method?

A

1 measure mass of container
2 add chemical to container and weigh container
3 calculate mass of the chemical
4 transfer chemical and reweigh empty container
5 calculate the mass of chemical transferred

29
Q

maximum error formula

A

uncertainty / total volume x100
e.g. 0.2 / 250 x 100 = 0.08%