Key Definitions 1.2 Flashcards

0
Q

Electron shielding

A

The repulsion between electrons in different inner shells. Shielding reduces the net attractive force from the positive nucleus on the outer-shell electrons.

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1
Q

The first ionisation energy

A

The energy required to remove one electron from in each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions

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2
Q

Successive ionisation energies

A

A measure of the energy required to remove each electron in turn.

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3
Q

A shell

A

A shell is a group of atomic orbitals with the same principal quantum number, n. Also known as a main energy level.

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4
Q

Principal quantum number

A

n, is a number representing the relative overall energy of each orbital

This increases with distance from the nucleus. The sets of orbitals with the same n-value are referred to as electron shells or orbitals.

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5
Q

Atomic orbital

A

A region within an atom that can hold up to two electrons with opposite spins.

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6
Q

Sub-shell

A

A group of the same type of atomic orbitals within a shell

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7
Q

Electron configuration

A

The arrangement of electrons in an atom.

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8
Q

Compound

A

A substance formed from two or more chemically bonded elements in a fixed ratio.

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9
Q

Ionic bond

A

The electrostatic attraction between oppositely charged ions.

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10
Q

Giant ionic lattice

A

A three-dimensional structure of oppositely charged ions, held together by strong ionic bonds.

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11
Q

A group

A

A vertical column in the periodic table. Elements in the same group have similar chemical properties and their atoms have the same number of electrons on their outer shell.

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12
Q

A covalent bond

A

A bond formed by as haired pair of electrons

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13
Q

A lone pair

A

An outer shell pair of electrons that is not involved in chemical bonding

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14
Q

A dative covalent bond

A

A shared pair of electrons which has been provided by one of the bonding atoms only

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15
Q

Electronegativity

A

A measure of the attraction of a bonded atom for the pair of electrons in a covalent bond

16
Q

Permanent dipole

A

A small charge difference across a bond that results from a difference in electronegativities of the bonded atoms.

17
Q

Polar covalent bond

A

A polar covalent bond has a permanent dipole

18
Q

A polar molecule

A

When the molecule has an overall dipole when you take into account any dipoles across the bond

19
Q

An intermolecular force

A

An attractive force between neighbouring molecules

20
Q

Permanent dipole-dipole force

A

A weak attractive force between permanent dipoles is neighbouring molecules

21
Q

Van der Waals’

A

Attractive forces between induced dipoles in neighbouring molecules

22
Q

Hydrogen bonds

A

A strong dipole-dipole attraction between an electron deficient hydrogen atom on one molecule and a lone pair on a highly electronegative atom on a different molecule

23
Q

Metallic bonding

A

The electrostatic attraction between positive metal ions and delocalised electrons

24
Q

Delocalised electrons

A

Electrons that are shared between more than two atoms

25
Q

A giant metallic lattice

A

A 3D structure of positive ions and delocalised electrons bonded together by strong metallic bonds.

26
Q

A simple molecular lattice

A

A 3D structure of molecules, bonded together by weak intermolecular forces

27
Q

A giant covalent lattice

A

A 3D structure of atoms bonded together by strong covalent bonds