Lab Exam 1 Flashcards

1
Q

Formulas for Delta G

A

Delta H - (delta S)(T)(1/1000)

Products - Reactants

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2
Q

First order formulas

A

t 1/2 = 0.693/k

Ln (Final / Initial) = -kt

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3
Q

Second order formulas

A

t 1/2 = 1 / (initial)(k)

1/final - 1/initial = kt

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4
Q

Zero order formulas

A

t 1/2 = inital / 2k

Initial - Final = kt

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5
Q

Delta H is

A

Enthalpy

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6
Q

Delta S is

A

Entropy

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7
Q

Delta G is

A

Reaction occuring or not

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8
Q

Delta H for:

Exo
Endo

A

(-)

+

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9
Q

Delta G for:

Spontaneous
Non Spontaneous

A

(-)

+

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10
Q

Delta S for:

More DISORDER
Less DISORDER

A

(+)

-

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11
Q

4 factors that effect rate

A
Concentration
Temp
Catalyst
Physical state - 
(PV)
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12
Q

Concentration goes up ….

A

Rate goes up

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13
Q

Temp goes up ….

A

Rate goes up

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14
Q

Catalyst ….

A

Rate goes up

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15
Q

Pressure goes up ….

A

Rate goes up

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16
Q

Volume goes up ….

A

Rate goes down

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17
Q

Mol ratio of oxalic acid with NaOH

A

1 (Oxalic) : 2 (NaOH)

18
Q

Rate of disappearance

A

R = - (1/coeff) [A]^order

19
Q

Rate of appearance

A

R = + (1/coeff) [A]^order

20
Q

Slope equation

A
  • Ea/R
21
Q

Activational energy formula

A

K2/K1 = -Ea/R (T2 - T1)(1/1000)

22
Q

Units of K in OVERALL FIRST ORDER

A

1/s

23
Q

Units of K in OVERALL SECOND ORDER

A

1/M . S

24
Q

Units of K in OVERALL THIRD ORDER

A

1/M^2 . S

25
Q

When concentration doubles and rate doubles it is a

A

FIRST ORDER REACTION

26
Q

When concentration doubles and rate quads it is a

A

SECOND ORDER REACTION

27
Q

When concentration doubles and rate stays the same it is a

A

ZERO ORDER REACTION

28
Q

Arrhenius equation originally

Arrhenius equation manipulated for Ln K

A

K = Ae^ -Ea/RT

Ln K = - (Ea/R)(1/T) + Ln A

29
Q

What is the mol ratio between CaCO3 and HCL

A

1 (CaCO3) : 2 HCL

30
Q

What is the % that quantative transfer does

A

99.9999%

31
Q

What is the number of sig figs in:

Buret
Graduated cylinder
Pipet
Beaker

A

4

3

4

2

32
Q

What goes on the graph x and y axis for:

Zero

First

Second

A

Zero:
x = t
y = inital [A]

First:
x = t
y = ln [A]

Second
x = t
y = 1/[A]

33
Q

What causes delta S to increases (More disorder)

A
(s) to (l) to (g)
Increase T 
Increase V 
Increase MW 
Increase Mol
34
Q

If the beaker gets hot it is

A

Exothermic

35
Q

If the beaker gets cold it is

A

Endothermic

36
Q

If you over titrate, your value will be

A

Smaller

37
Q

The Al in exp 19 converts what

A

Fe+3 to Fe +2

38
Q

What is the reducing agent and what is the oxidising agent in exp 19

A

Ce+4 = oxidising

Fe+2 = reducing

39
Q

What is the redox reaction in exp 19

A

Ce+4 + Fe+2 ——- Ce+3 + Fe+3

40
Q

Thymol is an indicator used for

What does its colour change to

A

CaCO3 = tums

Red to yellow

41
Q

What indicator is used in exp 19

What does its colour change to

A

Oxidation reduction indicator

Red to colourless/light blue