Lewis Acids And Bases Flashcards

1
Q

Lewis acid

A

Electron pair acceptor

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2
Q

Lewis base

A

Electron pair donor

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3
Q

Hard LA and LB

A

Small and highly charged

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4
Q

Soft LA and LB

A

Large, polarisable electron density

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5
Q

How do EDG affect LA and LB strength

A

Increases base strength and decreases acid strength

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6
Q

How do the presence of large group affect LB strength

A

Weaker base

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7
Q

How does the presence of a small/large R group affect the strength of LA

A

Large R = weaker LA
Small R = stronger LA

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8
Q

Frustrated Lewis pairs

A

Sterically hindered strong LA and sterically hindered strong LB makes a frustrated pair that has unquenched reactivity

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