Lewis Model Flashcards

1
Q

Covalent bond

A

Electron pairs are shared equally between atoms

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2
Q

Polar covalent

A

Electron pairs share unequally giving a polar covalent bond

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3
Q

Ionic bonding

A

Electron(s) transferred from one atom to another

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4
Q

Who is Gilbert Lewis?

A

Developed the theory of covalent bonding

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5
Q

Lewis symbols

A

Simple way of showing valence electrons.
Simple use of electrons as dots or crosses

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6
Q

Chemical bend length

A

Chemical bonds are measured using electron diffraction techniques. The length of a chemical bond is not fixed

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7
Q

Lewis structure

A

Representation f the formation of covalent bonds using Lewis symbols

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8
Q

Advantages and
Disadvantages of Lewis Model

A

Adv: Provides a simple way to describe bonding
Prediction of bond order
Can be extended to predict molecular shape (VSEPR)
Disadv: Doesn’t explain how bonding occurs
Doesn’t always work - many molecules don’t follow the octet rule and yet are stable.
Hypervalency
Bonding in transition metal compounds
Doesn’t explain paramagnetism of oxygen

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9
Q

Electronegativity

A

The more electronegative, the more likely it will pull electrons towards it

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10
Q

Octet rule

A

Atoms gain, lose or share electrons until they are surrounded by eight electrons
No vacant orbitals: no reactivity

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11
Q

Exceptions to octet rule

A
  • Molecules with odd numbers of electrons
  • Reduced octets (i.e. less than 8 electrons)
  • Expanded octets (i.e more than 8 electrons)
  • Not followed usually by s- d- and f- block elements
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12
Q

Octet exception - Odd number

A

O=Cl=O ->
N=O -> 9electrons
O=N=O

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13
Q

Octet exception - reduced octet

A

Cl-Be-Cl ->Be has 4 electrons
BF3 ->B has 6 electrons
AlCl3 -> Al has 6 electrons

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14
Q

Octet exception - Expanded octet

A

SF6 -> S has 12 electrons
PCl5 -> P has 10 electrons
IF7 -> I has 14 electrons

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