Mechanisms 2 Flashcards Preview

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Flashcards in Mechanisms 2 Deck (66):
1

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*Grignard/organolithium addition to α,β-unsaturated carbonyls

2

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*Cuprate addition to α,β-unsaturated carbonyls

3

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*Acidic halogenation

4

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Basic halogenation

5

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Basic halogenation LD

6

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*Haloform reaction

7

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*Hell-Volhard-Zelinsky (HVZ)

8

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*Alkylation

9

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*Acetoacetic ester synthesis

10

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*Malonic ester synthesis

11

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*Enamine alkylation

12

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*Aldol reaction

13

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*Aldol Condensation

14

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*Directed Aldol reaction

15

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*Directed Aldol Condensation

16

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*Claisen condensation

17

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*Claisen condensation LDA

18

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*Directed Claisen condensation

19

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*Directed Claisen condensation LDA

20

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*Mannich reaction

21

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*Robinson Annulation

22

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*Kiliani-Fischer synthesis (no mechanism required for Lindlar reduction)

23

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*Wohl degradation

24

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Ruff degradation

25

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*Br2, H2O oxidation to aldonic acid

26

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*Epimerization

27

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*Glycoside formation

28

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*Amino acid formation via SN2 with ammonia

29

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*Amino acid formation via Gabriel/malonic ester synthesis

30

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*Strecker amino acid synthesis

31

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*Boc protection of amines

32

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*Peptide formation

33

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Boc deprotection

34

*Grignard/organolithium addition to α,β-unsaturated carbonyls

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35

*Cuprate addition to α,β-unsaturated carbonyls

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36

*Acidic halogenation

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37

Basic halogenation

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38

Basic halogenation LD

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39

*Haloform reaction

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40

*Hell-Volhard-Zelinsky (HVZ)

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41

*Alkylation

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42

*Acetoacetic ester synthesis

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43

*Malonic ester synthesis

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44

*Enamine alkylation

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45

*Aldol reaction

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46

*Aldol Condensation

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47

*Directed Aldol reaction

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48

*Directed Aldol Condensation

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49

*Claisen condensation

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50

*Claisen condensation LDA

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51

*Directed Claisen condensation

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52

*Directed Claisen condensation LDA

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53

*Mannich reaction

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54

*Robinson Annulation

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55

*Kiliani-Fischer synthesis (no mechanism required for Lindlar reduction)

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56

*Wohl degradation

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57

Ruff degradation

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58

*Br2, H2O oxidation to aldonic acid

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59

*Epimerization

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60

*Glycoside formation

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61

*Amino acid formation via SN2 with ammonia

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62

*Amino acid formation via Gabriel/malonic ester synthesis

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63

*Strecker amino acid synthesis

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64

*Boc protection of amines

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65

*Peptide formation

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66

Boc deprotection

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