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Organic Chemistry > Mechanisms 2 > Flashcards

Mechanisms 2 Flashcards

1
Q
A

*Grignard/organolithium addition to α,β-unsaturated carbonyls

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2
Q
A

*Cuprate addition to α,β-unsaturated carbonyls

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3
Q
A

*Acidic halogenation

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4
Q
A

Basic halogenation

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5
Q
A

Basic halogenation LD

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6
Q
A

*Haloform reaction

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7
Q
A

*Hell-Volhard-Zelinsky (HVZ)

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8
Q
A

*Alkylation

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9
Q
A

*Acetoacetic ester synthesis

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10
Q
A

*Malonic ester synthesis

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11
Q
A

*Enamine alkylation

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12
Q
A

*Aldol reaction

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13
Q
A

*Aldol Condensation

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14
Q
A

*Directed Aldol reaction

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15
Q
A

*Directed Aldol Condensation

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16
Q
A

*Claisen condensation

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17
Q
A

*Claisen condensation LDA

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18
Q
A

*Directed Claisen condensation

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19
Q
A

*Directed Claisen condensation LDA

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20
Q
A

*Mannich reaction

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21
Q
A

*Robinson Annulation

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22
Q
A

*Kiliani-Fischer synthesis (no mechanism required for Lindlar reduction)

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23
Q
A

*Wohl degradation

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24
Q
A

Ruff degradation

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25
Q
A

*Br2, H2O oxidation to aldonic acid

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26
Q
A

*Epimerization

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27
Q
A

*Glycoside formation

28
Q
A

*Amino acid formation via SN2 with ammonia

29
Q
A

*Amino acid formation via Gabriel/malonic ester synthesis

30
Q
A

*Strecker amino acid synthesis

31
Q
A

*Boc protection of amines

32
Q
A

*Peptide formation

33
Q
A

Boc deprotection

34
Q

Describe the

*Grignard/organolithium addition to α,β-unsaturated carbonyls

A
35
Q

Describe the

*Cuprate addition to α,β-unsaturated carbonyls

A
36
Q

Describe the

*Acidic halogenation

A
37
Q

Describe the

Basic halogenation

A
38
Q

Describe the

Basic halogenation LD

A
39
Q

Describe the

*Haloform reaction

A
40
Q

Describe the

*Hell-Volhard-Zelinsky (HVZ)

A
41
Q

Describe the

*Alkylation

A
42
Q

Describe the

*Acetoacetic ester synthesis

A
43
Q

Describe the

*Malonic ester synthesis

A
44
Q

Describe the

*Enamine alkylation

A
45
Q

Describe the

*Aldol reaction

A
46
Q

Describe the

*Aldol Condensation

A
47
Q

Describe the

*Directed Aldol reaction

A
48
Q

Describe the

*Directed Aldol Condensation

A
49
Q

Describe the

*Claisen condensation

A
50
Q

Describe the

*Claisen condensation LDA

A
51
Q

Describe the

*Directed Claisen condensation

A
52
Q

Describe the

*Directed Claisen condensation LDA

A
53
Q

Describe the

*Mannich reaction

A
54
Q

Describe the

*Robinson Annulation

A
55
Q

Describe the

*Kiliani-Fischer synthesis (no mechanism required for Lindlar reduction)

A
56
Q

Describe the

*Wohl degradation

A
57
Q

Describe the

Ruff degradation

A
58
Q

Describe the

*Br2, H2O oxidation to aldonic acid

A
59
Q

Describe the

*Epimerization

A
60
Q

Describe the

*Glycoside formation

A
61
Q

Describe the

*Amino acid formation via SN2 with ammonia

A
62
Q

Describe the

*Amino acid formation via Gabriel/malonic ester synthesis

A
63
Q

Describe the

*Strecker amino acid synthesis

A
64
Q

Describe the

*Boc protection of amines

A
65
Q

Describe the

*Peptide formation

A
66
Q

Describe the

Boc deprotection

A

Organic Chemistry (2 decks)

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