Mechanisms 2 Flashcards Preview

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Flashcards in Mechanisms 2 Deck (66):
1

*Grignard/organolithium addition to α,β-unsaturated carbonyls

2

*Cuprate addition to α,β-unsaturated carbonyls

3

*Acidic halogenation

4

Basic halogenation

5

Basic halogenation LD

6

*Haloform reaction

7

*Hell-Volhard-Zelinsky (HVZ)

8

*Alkylation

9

*Acetoacetic ester synthesis

10

*Malonic ester synthesis

11

*Enamine alkylation

12

*Aldol reaction

13

*Aldol Condensation

14

*Directed Aldol reaction

15

*Directed Aldol Condensation

16

*Claisen condensation

17

*Claisen condensation LDA

18

*Directed Claisen condensation

19

*Directed Claisen condensation LDA

20

*Mannich reaction

21

*Robinson Annulation

22

*Kiliani-Fischer synthesis (no mechanism required for Lindlar reduction)

23

*Wohl degradation

24

Ruff degradation

25

*Br2, H2O oxidation to aldonic acid

26

*Epimerization

27

*Glycoside formation

28

*Amino acid formation via SN2 with ammonia

29

*Amino acid formation via Gabriel/malonic ester synthesis

30

*Strecker amino acid synthesis

31

*Boc protection of amines

32

*Peptide formation

33

Boc deprotection

34

*Grignard/organolithium addition to α,β-unsaturated carbonyls

35

*Cuprate addition to α,β-unsaturated carbonyls

36

*Acidic halogenation

37

Basic halogenation

38

Basic halogenation LD

39

*Haloform reaction

40

*Hell-Volhard-Zelinsky (HVZ)

41

*Alkylation

42

*Acetoacetic ester synthesis

43

*Malonic ester synthesis

44

*Enamine alkylation

45

*Aldol reaction

46

*Aldol Condensation

47

*Directed Aldol reaction

48

*Directed Aldol Condensation

49

*Claisen condensation

50

*Claisen condensation LDA

51

*Directed Claisen condensation

52

*Directed Claisen condensation LDA

53

*Mannich reaction

54

*Robinson Annulation

55

*Kiliani-Fischer synthesis (no mechanism required for Lindlar reduction)

56

*Wohl degradation

57

Ruff degradation

58

*Br2, H2O oxidation to aldonic acid

59

*Epimerization

60

*Glycoside formation

61

*Amino acid formation via SN2 with ammonia

62

*Amino acid formation via Gabriel/malonic ester synthesis

63

*Strecker amino acid synthesis

64

*Boc protection of amines

65

*Peptide formation

66

Boc deprotection