Mixture thermodynamics Flashcards

1
Q

Define mixture

A

System in which all components have similar mole fractions

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2
Q

Define solution

A

One of components is in large excess => component in excess is the solvent, remaining components are solutes

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3
Q

Describe the mixing process

A

Two pure components are mixed at same temp and pressure so final pressure is the same

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4
Q

Describe the phase equilibrium of binary mixtures

A

Two phases at the same pressure and temperature are in equilibrium when the chemical potential of each species is the same in both phases.

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5
Q

Describe an ideal mixture

A

No change in total volume on mixing => total volume equal to sum of components
=> molecular size and interactions of each component of the mixture are the same

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6
Q

What does internal energy depend on?

A

Only temperature

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