Organic Chemistry Flashcards
Functional grouo
Is an atom or a group of atoms responsible for the typical chemical reaction of a molecule
Naming
Prefixes
1 meth 2 eth 3 prop 4 but 5 pent 6 hex 7 sept 8 oct
Homologous series
Is a family of organic compounds with the same functional group but differ by CH2.
Same general formula
Trend in physical properties
Similar chemical oroperties
Isomers
Same molecular formula but different atom arrangement
Positional isomerism
The functional group is attached to the main chain at different points
Functional group isomerism
Different functional group
Chain isomerism
The hydrocarbon chain is arranged differently (branched)
Alkanes
Saturated hydrocarbons with only carbon-carbon and carbon-hydrogen single bonds.
CnH2n+2
Polarity of alkanes
Almost non-polar > only van der Waals
The larger the molecule the stringer the van der Waals
Boiling points of alkanes
The longer the chain the stronger the van der Waals the higher the boiling points
Solubility if alkanes
Insoluble in water because water is held by hydrogen bond (much stronger)
Soluble in non-polar liqiuds
Fractional distillation
To separate the mixture of crude oil by heating and collecting the fractions that boil over different ranges if temperature
Fractionating tower
Bubble caps- condense here
Shorter chain collected near the top
Purpose of cracking
To produce shorter, more useful chains
To produce alkenes
Thermal cracking
High cost
High temp 700-1200K
High pressure 7000kPa
Produce alkane + alkene