Paper Two Flashcards
How do calculate any rate
Change in quality/time
What are two ways to investigate rate of reaction
Hydrochloric acid + sodium thiosulphate causes solution to go cloudy
Measure time for cross to disappear; repeat at different temperatures
The hotter the temperature the less time it takes for cross to disappear
Reaction 2:
Measure volume of gas produced by attaching gas syringe to reaction vessel
How do you increase rates of reaction
Increase surface area/concentration/pressure
How does temperature increase rate of reaction
Increase temperature: particles move faster, collide more frequently and with more energy so there are more frequent successful collisions
What does FSC mean(rate of reaction)
Frequency successful collisions
How does a catalyst decrease reaction time
Reduces activation energy
Collisions more likely to be successful
How is crude oil formed
Crude oil is formed over millions of years from the remains of tiny sea creatures called plankton which were buried in the mud and pressure causes it to turn into crude oil
What is crude oil made up of
Mixture of hydrocarbons and it is a mixture of molecules called hydrocarbons(hydrogen and carbon only)
How many carbon and hydrogen bonds in methane and what makes them bond
Covalent bond
One carbon atom
Four hydrogen atoms
What are hydrocarbons like methane and ethane called
Alkanes
What is the general formula of alkanes
CNH2N+2
Describe alkanes
Scientist say that alkanes are saturated molecules. That is because the carbon atoms are full bonded to hydrogen atoms
What does viscosity tell us about hydrocarbon
How thick the fluid is.
Fluids with a high viscosity flow slowly.
As the size of the hydrocarbon molecules increases, the molecules get more viscous. Very long chain hydrocarbons flow very slowly.
What does flammability tell us about hydrocarbon
How easily a hydrocarbon combusts(burns)
Short chain hydrocarbons are extremely flammable
As the size of the hydrocarbon molecules increases, the molecules get less flammable, long chain hydrocarbons are very difficult to burn
What does boiling point tell us about hydrocarbons
Boiling point - the temperature at which a liquid turns into a gas
Short chain hydrocarbons have low boiling points
All of the hydrocarbons here are gasses at room temperature(methane,ethane,propane,butane)
As the size of the hydrocarbon molecules increases, the boiling point also increases so very long chain hydrocarbons have very high boiling points
What do hydrocarbons do when they are combusted(Burned)
Release energy
What happens during combustion of hydrocarbons
Carbon and hydrogen atoms in the fuel react with oxygen. The carbon and hydrogen are oxidised. If the oxygen is unlimited, this reaction produces carbon dioxide and water. This is called a complete combustion
What is the equation for the complete combustion of methane
Methane + oxygen - carbon dioxide + water
What is and happens fractional distillation
In fractional distillation crude oil is separated into fractions. Fractions contain hydrocarbons with a similar number of carbon atoms.
What are the steps of fractional distillation
Firstly, the crude oil is heated to a very high temperature. This causes the crude to boil. All of the hydrocarbons evaporate and turn into a gas. The crude oil vapour is now fed into the fractional distillation column. The column is hotter at the bottom and cooler at the top. The hydrocarbon vapours now rise up the column, hydrocarbons condense(turn back into a liquid) when they reach their boiling point. Then the liquid fractions are removed. The remaining hydrocarbons continue moving up the column and these now condense when they reach their boiling points. Very long chain hydrocarbons have very high boiling points. These hydrocarbons are removed from the bottom of the column and very short chain hydrocarbon have a very low boiling point and these do not condense. They are removed from the top of the column as gasses
What powers cars
Petrol and diesel
What is used to power planes
Kerosene
What is used to power ships
Heavy fuel oil
What is liquid fed petroleum gas used for
Camping stoves
What are Some fractions used for
Feedstock for the petrochemical industry. A feedstock is a chemical that is used to make other chemicals.
Solvents, lubricants, detergents and polymers
Name each proportion of gas in our atmosphere(oxygen and nitrogen)
Oxygen-21%
Nitrogen-71%
What happpend millions of years ago to form the earths atmosphere
4600 million years ago, in the first billion years, there was intense volcanic activity. These volcanoes released the gasses that formed the atmosphere. One of these gasses was water vapour. As the Earth cooled, the water vapour condensed to form the oceans. Volcanoes also released a lot of carbon dioxide so in this early age, the earths atmosphere consisted mainly of carbon dioxide with little or no oxygen
What do volcanoes release a lot of
Carbon dioxide
Which other planets were similar to earth millions of years ago
The earth’s atmosphere then was very much like the atmospheres of mars and Venus today.
What gasses do volcanoes release
Carbon dioxide(Loads)
Nitrogen which gradually built up in the atmosphere
Small amounts of methane and ammonia
What is different about the current atmosphere to the atmosphere of the early earth
Early earth:
-mostly carbon dioxide
-small amount of nitrogen
Earth today:
-a lot of nitrogen
-1/5 oxygen
-small amount of carbon dioxide
How did the atmosphere change from millions of years ago to now
Some carbon dioxide from volcanoes dissolved in the oceans to form a weak acid. This reacted with minerals in the sea to form precipitates. Over time, this formed sediments of carbonate rock on the sea bed. Some of the carbon dioxide in the sea was used to make corals and shells of organisms such as mussels. When these die they formed the sedimentary rock limestone. This also removed carbon dioxide from the atmosphere. So carbon dioxide levels began to fall.
Where did the oxygen come from as there was none in early earth but ??%
21%
2.7 billion years ago, photosynthetic algae first evolved in the oceans.
Photosynthesis produced oxygen which entered the atmosphere.
Over the following billion years, plants evolved. This increased the amount of oxygen in the atmosphere.
At some point the level of oxygen reached the point where animals could evolves. As well as producing oxygen, carbon dioxide is absorbed
What are the examples of fossil fuels
Coal
Oil
Gas
How long does it for fossil fuels too be formed
Over millions of year. Fossil fuels are non-renewable. If we keep using them, then they will run out.
How is coal formed
Formed from the remains of ferns and tress. If those die in marshy wetlands then they do not decompose. That can due to a lack of oxygen or acidic conditions. These both prevent bacteria from carrying out decomposition. Over time the plant reminds over covered with sediment and compressed. High temperature and pressure creates coal.
How is crude oil formed
Crude oil is formed from plankton which are tiny plants and animals found in the sea. When these die, they settle in mud on the sea bed. If oxygen is not present they do not decompose. Over time, they are compressed by sediment. Heat and pressure then convert them into crude oil.
How is natural gas(mainly hydrocarbon methane) formed
We often find natural gas near deposits of oil. That’s because natural gas if from plankton in a similar way to oil. All fossil fuels contain trapped carbon, and that carbon was part of the carbon dioxide taken in by photosynthesis.
What are the percentages of water vapour, carbon dioxide and methane in the atmosphere.
Carbon dioxide - 0.04%
Methane - 0.0002%
Water vapour - the amount of water vapour in the atmosphere is variable and changes depending on the temperature.
What are water vapour, carbon dioxide and methane all examples of
Green house gasses
What is the greenhouse effect
Energy from the sun travels to the earth as short wavelength radiation e.g. ultraviolet and visible light. Some of the short wavelength radiation simply reflects back into space but most of it passes easily through the atmosphere. This is because short wavelength radiation does not interact strongly with the gas molecules in the atmosphere. The energy of the radiation is absorbed when it reaches the surface of the earth. The surface of the earth now radiates the energy as long wavelength radiation as infrared. Some of the long wavelength radiation interacts with the greenhouse gas molecules in the atmosphere. The energy in the long wavelength radiation is absorbed, as the energy is trapped in the atmosphere, this causes the temperature of the atmosphere to increase.
What is positive about the greenhouse effect
Keep the temperature warm enough to support life
Why are carbon dioxide and methane increasing
Human activity
How is carbon dioxide increasing
Burning fossil fuels e.g coal - electricity