reactions and reagents Flashcards

1
Q

benzene to chlorobenzene?

A

iron (III) chloride and chlorine

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2
Q

bromination?

A

iron (III) bromide and bromine

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3
Q

sulphonation?

A

c. sulphuric acid and reflux

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4
Q

alkylation?

A

AlCl3 and RCl and reflux

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5
Q

acylation?

A

AlCl3 and ROCl

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6
Q

benzene to nitrobenzene, nitrobenzene to aminobenzene?

A
  1. c. sulphuric acid, c. nitric acid and below 55c

2. Sn, c. HCl and reflux

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7
Q

benzaldehyde to benzyl alcohol?

A

NaBr4

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8
Q

alkene to alkane?

A

Ni
hydrogen
5atm

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9
Q

alkene to a halgenoalkane

A

hydrogen halide

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10
Q

alkane to halgenoalkane?

A

halogen

sunlight

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11
Q

halgenoalkane to an amine

A

c. ammonia

heat

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12
Q

halgenoalkane to a nitrile

A

NaCN
reflux
ethanol

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13
Q

acyl chloride to a primary amide

A

c. ammonia

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14
Q

acyl chloride to a secondary amide

A

primary amine

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15
Q

acyl choride to an ester

A

alcohol

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16
Q

CA to an ester

A

alcohol
proton
reflux

17
Q

ester to a CA

A

proton

reflux

18
Q

CA to acyl chloride

A

reflux

SCl2O

19
Q

primary alcohol to aldehyde

A

distil
acidified potassium dichromate ions
protons

20
Q

aldehyde to carboxylic

A

reflux
dichromate ions
sulphuric acid

21
Q

primary alcohol to alkene

A

aluminium oxide and 300c

22
Q

primary alcohol to halgenoalkane

A

c. sulphuric acid
NaBr
reflux

23
Q

halgenoalkane to primary alcohol

A

NaOH and reflux

24
Q

acylation electrophile formation?

A

RCCOCl + AlCl3 –> RCO^+ + AlCl4^-

25
Q

alkylation electrophile formation

A

RCl + AlCl3 –> R^+ + AlCl4^-

26
Q

sulphonation electrophile formation?

A

H2SO4 <=> H20 + SO3 (E)

27
Q

nitration electrophile formation?

A

HNO3 + 2H2SO4 –> NO2^+ + 2HSO4^- + H3O+

28
Q

bromination electrophile formation

A

Br2 gets polarised by benzenes delocalised electrons