Remediation Flashcards
PRG DEF
conc below which risk level acceptable
MCLG DEF
Residual water must meet before remediation complete under SDWA. Max level of no known adverse health effects. Non-enforceable
Def - CSM
Organise and communicate info on site characteristics (inc receptors), Conceptual site model
Thermal treatment (aka thermal desorption)
Soil placed in rotary kiln, heated to 1,100 oF. Volatilized contaminants, mixed with natural gas & incinerated in an afterburner. Can produce recyclable by-product soils. Efficiency up to 99%. Lower efficiencies for high water content, semi-volatile, and fine grained soils.
Asphalt Incorporation
Alt to thermal treatment. Lighter molecular weight (Lower volatility) chemicals volatilize while binders in the asphalt stabilize remaining contaminants.
Soil Stabilization
METALS and NON-VOLATILES. Soil mixed with stabilizing agents. If these are fly ash or cement process is termed pozzolanic encapsulation. Binds contaminants, reducing leaching potential.
Soil Vapor Extraction - pros and cons
Popular for volatiles. Done in Situ. Light NAPL. Stimulates aerobic biodegradation. explosive atm. NOT multicyclic compounds.
Phytoremediation
radiation, BTEX, TCE, multicyclic compounds, heavy metals. Longer term. cold and dry slows.
Thermal treatment not suitable for
Clorinated hyrocarbons as these may produce HCl(g) and undesirable byproducts. Which requires acid scrubbers, increases cost and complicates air permitting
Air Stripping
Most effecient and cost-effective. Semi-volatile organic compounds and metals -
liquid-phase carbon adsorption.
For high-capacity systems that recover
semi-volatile or non-volatile organics, biological treatment systems NUFF CHAT
Air Sparging
Injection wells introduce air via a compressor into wells that removes contaminants via “air stripping”, enhanced biodegradation or both. Requires “soil vapor extraction” for air rising from the wells. Generally uses vertical injection wells.
Oxidation things
Using strong electron accepting chems such as iron to recover PERC along interceptor trenches. Fentin reagent chemistry also used
Low profile tray-air strippers - benefits
More efficient and less maintenancy than packed tower air strippers.
Air sparging vs. groundwater recovery
better mass recovery and lower maintenancy but no hydraulic control.
fentin reagent chemistry
Uses H2O2 and Ferrous Ion (usually a ferrous sulfate?)