t6- rate of reaction Flashcards

1
Q

what is the rate of reaction

A

a measure of how quickly reactants are used up/products are formed

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2
Q

what is the collision theory

A

a chemical reaction can only happen if the reactant particles collide with each other with sufficient energy

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3
Q

what is activation energy

A

the minimum energy required for a successful collision

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4
Q

what are the 5 factors that affect RoR

A

temperature
concentration
pressure
SA
catalysts

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5
Q

what are 3 ways to measure ROR

A

loss in mass of reactants
vol of gas produced
time for solution to become opaque

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6
Q

what is the effect of increasing temperature on ROR

A

as temp increases kinetic energy of particles increases
particles move faster
so there are more successful collisions
increases ROR

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7
Q

what is the effect of increasing concentration on ROR

A

higher conc means more particles in a given volume
more successful collisions
increases ROR

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8
Q

what is the effect of increasing pressure on ROR

A

higher pressure means more particles in the same volume
more successful collisions
increases ROR

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9
Q

what is the effect of increasing SA:V on ROR

A

if solid reactants are powder, they have a bigger SA
increasing SA means particles are more exposed at the surface
frequency of collisions increases
increases ROR

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10
Q

what is a catalyst

A

increases the ROR without being used up itself
uses an alternate reaction pathway with a lower activation energy

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11
Q

what would the reaction profile of a catalyst look like

A

lower maximum of the curve (lower activation energy)

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12
Q

what is a reversible reaction

A

products can react together to produce the original reactants

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13
Q

when is dynamic equilibrium reached

A

in a closed system
forwards and backward reactions occur at the same rate
concentrations of products and reactants remain constant

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14
Q

what is le chateliers principle

A

if a system is at equilibrium and a change is made to the reaction, the equilibrium position will move to counteract the change and restore the equilibrium

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15
Q

what is the effect of changing concentration in equilibrium

A

increased conc of reactant means equilibrium position will move to the right so more products are formed
decreased conc of product means more reactants will react

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16
Q

what is the effect of changing temperature in equilibrium

A

increased temp means equilibrium position moves to the endothermic reaction
decreased temp means equilibrium position moves to the exothermic reaction

17
Q

what is the effect of changing pressure in equilibrium

A

increase in pressure means equilibrium position moves to the side with fewer molecules
decrease in pressure means equilibrium moves to the side with more molecules