t6- rate of reaction Flashcards
what is the rate of reaction
a measure of how quickly reactants are used up/products are formed
what is the collision theory
a chemical reaction can only happen if the reactant particles collide with each other with sufficient energy
what is activation energy
the minimum energy required for a successful collision
what are the 5 factors that affect RoR
temperature
concentration
pressure
SA
catalysts
what are 3 ways to measure ROR
loss in mass of reactants
vol of gas produced
time for solution to become opaque
what is the effect of increasing temperature on ROR
as temp increases kinetic energy of particles increases
particles move faster
so there are more successful collisions
increases ROR
what is the effect of increasing concentration on ROR
higher conc means more particles in a given volume
more successful collisions
increases ROR
what is the effect of increasing pressure on ROR
higher pressure means more particles in the same volume
more successful collisions
increases ROR
what is the effect of increasing SA:V on ROR
if solid reactants are powder, they have a bigger SA
increasing SA means particles are more exposed at the surface
frequency of collisions increases
increases ROR
what is a catalyst
increases the ROR without being used up itself
uses an alternate reaction pathway with a lower activation energy
what would the reaction profile of a catalyst look like
lower maximum of the curve (lower activation energy)
what is a reversible reaction
products can react together to produce the original reactants
when is dynamic equilibrium reached
in a closed system
forwards and backward reactions occur at the same rate
concentrations of products and reactants remain constant
what is le chateliers principle
if a system is at equilibrium and a change is made to the reaction, the equilibrium position will move to counteract the change and restore the equilibrium
what is the effect of changing concentration in equilibrium
increased conc of reactant means equilibrium position will move to the right so more products are formed
decreased conc of product means more reactants will react