Test 3 Chapter 14 Flashcards

1
Q

Heavy metals have to be treated differently why?

A

They cannot be degraded or destroyed

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2
Q

Sources of heavy metals in the environment

A

Mining activities, industry, agrochemicals, atmospheric deposition, waste disposal

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3
Q

Metals bioremediation mechanisms:

A

Metal immobilization
—Complexation (Bioaccumulation and biosoprtion)
—Precipitation
Solubilization (Bioleaching)

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4
Q

Mercury traits

A

Only common metal that is liquid at room temperature.

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5
Q

Where is mercury found in nature?

A

Cinnabar ore (HgS) in Spain and Italy

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6
Q

How does mercury methylation occur?

A

Mercury polution gets into the water and underwater archaea or bacteria what are then moved up the food chain to fish we eat.

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7
Q

Most toxic form of mercury?

A

methyl mercury

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8
Q

Bioaccumulation

A

the buildup of substances, such as pesticides or heavy metals, in an organism.

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9
Q

How does bioaccumulation occur?

A

when an organism absorbs a substance faster than it excretes it.

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10
Q

Results of bioaccumulation

A

results in the organism having a higher concentration than the surrounding environment.

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11
Q

Biomagnification

A

An increase in concentration of a pollutant from one link in a food chain to another.

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12
Q

Bio-magnification effect?

A

Predators will have more accumulation since they are at the top of food chain.

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13
Q

Number of Chromium oxidation states?

Most common ones

A

6 oxidation states

+3, +6 most common

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14
Q

Hexavalent Cr(VI)

A

Most toxic and most soluble form of Chromium

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15
Q

What does Cr (VI) cause?

A

Induces free-radical formation

Oxidative stress - DNA/membrane damage

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16
Q

Chromium (III)

A

essential nutrient for humans and shortages may cause heart conditions, disruptions of metabolisms and diabetes

17
Q

Chromium (III) overdose

A

uptake of too much chromium(III) can cause health effects as well, for instance skin rashes

18
Q

Chromium (VI)

A

Danger to human health, mainly steel and textile industry. And smokers.

19
Q

Bio-immobilization

A

Direct reductive precipitation - microbes change valency

Indirect reductive precipitation - microbes reduce other Terminal electron acceptor to precipitate heavy metals

20
Q

Indirect reductive precipitation

A

Microbial reduction of other terminal electron acceptors result in abiotic reduction and preciptation of heavy metals.
Useful in above-ground and in situ treatments.

21
Q

Direct reductive precipitation

A

using microbes to precipitate heavy metals by changing their valency
Useful in above-ground and in situ treatments