Thermal Physics Flashcards

1
Q

What is internal energy?

A

The sum of randomly distributed kinetic energies and potential energies of particles in a body.

For example in a glass of water the kinetic is is the energy associated with movement, and the potential energy is associated with any forces or interactions between the particles, such as electrostatic attraction or repulsion.

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2
Q

What factors affect the kinetic and potential energy of particles?

A

Kinetic - temperature

Potential - intermolecular forces

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3
Q

What is a fluid

A

a substance that can flow

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4
Q

What is the first law of thermodynamics?

A

The increase in internal energies of a system = the thermal energy added to the system - the work done by the system

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5
Q

When a gas expands, what happens and why.

A

The The gas does work on the surroundings. The force = pressure * piston area
The work done on the piston also = Forces * distance
substitute F = pA you get
change in work = pressure * change in volume

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6
Q

What happens when substances are heated?

A
  • Thermal energy is supplied to the particles
  • increasing internal energy U
  • increasing average kinetic energy

Thermal energy = mass * specific heat capacity * change in temperature(kelvin)

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7
Q

What is specific heat capacity?

A
  • A fundamental property of a material
  • The amount of thermal energy required to raise the temperature of 1 kg of a substance by 1 °C (or 1 K) without a change of state
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8
Q

What is specific latent heat?

A

The amount of thermal energy required to change the state of 1kg of a material, without a change in temperature, at a specified ambient pressure.

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9
Q

What is the amount of energy required to change the state of a substance.

A

mass * specific latent heat

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10
Q

What is Boyle’s Law?

A

for a fixed mass of an ideal gas at a constant temperature,

pressure is inversely proportional to volume.

p1V1 = p2V2

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11
Q

What is Amonton’s law?

A

The pressure of a fixed mass and fixed volume of a gas is directly proportional to the absolute temperature of the gas.

p1/T1 = p2/T2

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12
Q

What is Charles Law?

A

At constant pressure, the volume of a fixed mass of an ideal gas is directly proportional to its absolute temperature.

v1/T1 = v2/T2

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13
Q

What is absolute zero?

A

The temperature when all molecular motion ceases, and the pressure of a gas drops to zero.

0 Kelvin or -273.15°C

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14
Q

What is standard room temperature and pressure?

A

0 degrees Celsius and 1.01 *10^5 Pa (1 atm)

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15
Q

What is room temperature and pressure?

A

25 degrees Celsius and 1 atm

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16
Q

What is Avogadro’s law

A

the volume of a gas is directly proportional to the number of moles of the gas.

V1/n1 = V2/n2

17
Q

What is Avogadro’s constant?

A

The number of particles present in one mole of a substance

18
Q

What is the Boltzmann constant

A

The molar gas constant / Avogadro’s constant

19
Q

How do you measure the number of particles in a mass?

A

Molar mass = mass of one mole * mass of one molecule

number of moles = mass of a gas / molar mass

number of particles = mass of gas / mass of one molecule

20
Q

What is an ideal gas

A

There is
- a large number of small identical hard spherical molecules
- The volume of molecules is much smaller than the volume of the container
- all collisions are elastic and frictionless
- Movements obey Newtons laws
- Average distance between the molecules is very much larger than the size of the molecules
- they are moving in random directions with a distribution of velocities
- There are no intermolecular forces between collisions
- The only force on the molecules are those that determine the collisions between them and the walls
- there are no long range forces between gas and surroundings
- Time between collisions&raquo_space; time collidng

21
Q

What is an isothermal change?

A

A change that occurs at a constant temperature. This means that internal energy stays constant, so Q = W, meaning any transfer of energy leads to work being done and vice versa. It obeys Boyle’s Law.

22
Q

what is thermal equilibrium

A

no net flow of (thermal) energy (between two or more bodies) (1) bodies at same temperature