Thermodynamics Flashcards

1
Q

energy of the molecules
comprising the substance.

A

Internal energy

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2
Q

Kinetic and potential energy
associated with a substance

A

Internal energy

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3
Q

Energy influenced by macroscopic position, configuration, or motion

A

External energy

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4
Q

Divides the system and the surroundings

A

Boundary

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5
Q
A

System

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6
Q
A

Surroundings

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7
Q

does not permit the transfer of matter between the system and its
surroundings

A

Closed system

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8
Q
A

Open system

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9
Q

Properties that depend on quantity of materials

A

Extensive properties

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10
Q

Properties independent of the quantity of
material

A

intensive properties

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11
Q

A static condition, the absence of change

A

Equilibrium

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12
Q

Any tendency toward change is caused by a ____

A

driving force

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13
Q

Explain reversible processes

A

*A process is reversible when its direction can be reversed at any point by an infinitesimal change in external conditions.
*Ideal in that it produces maximum work with minimum amount of effort
*Frictionless

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14
Q

Explain steady-state processes

A

conditions within the control volume
do not change with time

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15
Q

homogeneous region of matter

A

Phase

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16
Q

The ______ at equilibrium is established when its temperature, pressure, and the compositions of all phases are fixed.

A

intensive state of a system

17
Q

Where two phases coexist in
equilibrium.

A

Region

18
Q

Coexisting phases are connected by the horizontal segment of the isotherm

A

Saturated

19
Q

Basis of PVT diagrams

A

Equation of state

20
Q

Relates pressure, molar or specific volume, and temperature for a pure homogeneous fluid at equilibrium.

A

Equation of state

21
Q

Relates pressure, molar or specific volume, and temperature for a pure homogeneous fluid at equilibrium.

A
22
Q

Relates pressure, molar or specific volume, and temperature for a pure homogeneous fluid at equilibrium.

A
23
Q

Fluid with both compressibility and expansivity constants equal to zero

A

incompressible fluid

24
Q

Validity of Ideal Gas Law

A

P=0, T=infinite

25
Q

Measure of the deviation of the real-gas molar volume from its ideal-gas value

A

compressibility factor

26
Q

PV/RT

A

compressibility factor

27
Q

A mixture in which the composition of coexisting vapor and liquid phases are the same

A

Azeotropic mixture

28
Q

Entropy

A

Measure of disorder within a system.