Topic 1 - Chemical Equilibrium Flashcards

1
Q

What is Equilibrium?

A

a state of a chemical reaction that is reached when the forward and reverse reactions are happening at equal rates

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2
Q

During equilibrium, the rate of _________ = the rate of ___________

A

Dissolution; precipitation

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3
Q

True or False: The concentrations of reactants and products at equilibrium remain constant

A

True

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4
Q

K = equilibrium constant

Written as an equation, what is K =?

A

K = [products] / [reactants]

  • concentrations should be raised to the power of the stoichiometry
  • pure solid and pure liquid states = 1
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5
Q

When k &laquo_space;1, the concentration of _____ is greater than the concentration of _______.

A

Reactants; Products

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6
Q

When k&raquo_space; 1, the concentration of _____ is greater than the concentration of _______.

A

Products; Reactants

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7
Q

If the forward reaction K = x, the reverse reaction K = ?

A

The reverse reaction K = 1/x

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8
Q

If a new chemical reaction’s stoichiometric coefficients are n times the original reaction’s stoichiometric coefficients, what is the formula to calculate the new K value?

A

K (new) = K (old) ^ n

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9
Q

When combining 2 reactions together, you ____ the 2 original K values to get the new K value.

A

multiply

K (new) = K (1) * K (2)

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10
Q

When k = 10^8, which direction is the reaction heading?

A

Forward, towards the products

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11
Q

When K = 10^-10, which direction is the reaction heading?

A

Backwards, towards the reactants

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12
Q

K value represents solution concentrations AT equilibrium, while Q value represents solution concentrations ______________.

A

NOT at equilibrium

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13
Q

Q < K means that the reaction is moving _______ and there is too much of _________.

A

Forwards; Reactants

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14
Q

Q = K means….

A

It has reached equilibrium

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15
Q

Q > K means the reaction is moving ________ and there is too much of ________.

A

Backwards; Products

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16
Q

Pure _____ and _______ are not included in the equilibrium constant expression.

A

Solids; Liquids

17
Q

Changing the Concentration of reactants or products is considered a stress to the system.

When you increase the concentration of reactants, the reaction shifts to the _________.

When you decrease the concentration of reactants, the reaction shifts to the __________.

A

Right; Left

18
Q

Changing the Concentration of reactants or products is considered a stress to the system.

When you increase the concentration of products, the reaction shifts to the _________.

When you decrease the concentration of products, the reaction shifts to the __________.

A

Left; Right

19
Q

Only when ________ changes does the value of K also change.

A

Temperature

20
Q

Exothermic reactions = heat as a ______

Endothermic reactions = heat as a _____

A

Product; Reactant