Topic 2 Flashcards

1
Q

What is ionic bonding ?

A

Ionic bonding is the electrostatic attraction between positive and negative ions

It is a relatively strong attraction

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2
Q

How are ionic compounds held together ?

A
  • They are held together in a giant lattice
  • Its a regular structure that extends in all directions in a substance
  • Electrostatic attraction between positive and negative ions hold the structure together
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3
Q

State properties of ionic substances

A
  • high melting and boiling point (strong electrostatic forces between oppositely charge ions)
  • Do not conduct electricity when solid (ions in fixed positions)
  • Conduct electricity when molten or dissolved in water - ions are free to move
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4
Q

How are ionic compounds formed ?

A

Reaction of a metal with a non-metal

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5
Q

What is covalent bond ?

A

Covalent bond is a shared pair of electrons between two atoms

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6
Q

Describe the structure and properties of simple molecular covalent substances

A
  • Do no conduct electricity (no ions)
  • Small molecules
  • Weak intermolecular forces, therefore: low melting and boiling points
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7
Q

How do intermolecular forces change as the mass/size of the molecules increases ?

A

They increase. That causes melting and boiling points to increase as well (more energy needed to overcome these forces)

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8
Q

What are polymers ?

A

Polymers are very large molecules (>100s , 1000s of atoms) with atoms linked by covalent bonds

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9
Q

What are giant covalent substances? Give examples

A
  • Solids , atoms covalently bonded together in a giant lattice
  • High melting and boiling points - strong covalent bonds
  • Mostly don’t conduct electricity (no delocalised electron)
  • Diamond , graphite , silicon dioxide
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10
Q

Describe and explain the properties of allotropes of carbon - Diamond

A
  • Four, strong covalent bonds for each carbon atom
  • Very hard (strong bonds)
  • Very high melting point (strong bonds)
  • Does not conduct electricity (no delocalised electrons)
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11
Q

Describe and explain the properties of allotropes of carbon - Fullerenes

A
  • hollow shaped molecules
  • based on hexagonal rings but may have 5 or 7 - carbon rings
    -The first fullerene to be discovered was Buckminsterfullerene (C60) which has a spherical shape.
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12
Q

Describe and explain the properties of allotropes of carbon - Graphite

A
  • three covalent bonds for each carbon atom
  • layers of hexagonal rings
  • high melting point
  • layers free to slide as weak intermolecular forces between layers; soft, can be used as lubricant
  • conduct thermal and electricity due to one delocalised electron each carbon atom

Graphene - a single layer of graphite

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13
Q

Describe and explain the properties of allotropes of carbon - Nanotubes

A
  • cylindrical fullerene with high length to diameter ratio
  • high tensile strength (strong bonds)
  • conduct electricity (delocalised electrons)
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14
Q

What is metallic bonding ?

A

Forces of attraction between delocalised electrons and nuclei of metal ions

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15
Q

Describe properties of metals

A
  • high melting/boiling points (strong forces of attraction)
  • good conductors of heat and electricity (delocalised electrons)
  • Malleable , soft (layers of atoms can slide over eachother whilst maintaining the attraction forces)
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16
Q

What are alloys ? Why are they harder than pure metals?

A

Mixture of metals with other elements , usually metals

Different sizes of atoms distorts the layers , so they cant slide over each other, therefore alloys are harder than pure metals

17
Q

What are the limitations of the simple model?

A

There are no forces between spheres and atoms , molecules and ions are solid spheres - this is not true

18
Q

What does the amount of energy needed to change state from solid to liquid or liquid to gas depend on?

A

The strength of the forces between the particles of the substance. The nature of the particles involved depends on the type of bonding and the structure of the substance . The stronger the forces between the particles the higher the melting point and boiling point of the substance

19
Q

A pure substance will melt or boil at …? What about the mixture?

A

A fixed temperature

A mixture will melt over a range of temperatures

20
Q

What are the three states of matter ?

A

Solid, liquid , gas

21
Q

Characteristics of polymers

A

Most polymers are solids at room temp
The intermolecular forces of attraction bettwen polymer molecules are strong
Polymers have a high meting point