Topic 2 Flashcards
What is ionic bonding ?
Ionic bonding is the electrostatic attraction between positive and negative ions
It is a relatively strong attraction
How are ionic compounds held together ?
- They are held together in a giant lattice
- Its a regular structure that extends in all directions in a substance
- Electrostatic attraction between positive and negative ions hold the structure together
State properties of ionic substances
- high melting and boiling point (strong electrostatic forces between oppositely charge ions)
- Do not conduct electricity when solid (ions in fixed positions)
- Conduct electricity when molten or dissolved in water - ions are free to move
How are ionic compounds formed ?
Reaction of a metal with a non-metal
What is covalent bond ?
Covalent bond is a shared pair of electrons between two atoms
Describe the structure and properties of simple molecular covalent substances
- Do no conduct electricity (no ions)
- Small molecules
- Weak intermolecular forces, therefore: low melting and boiling points
How do intermolecular forces change as the mass/size of the molecules increases ?
They increase. That causes melting and boiling points to increase as well (more energy needed to overcome these forces)
What are polymers ?
Polymers are very large molecules (>100s , 1000s of atoms) with atoms linked by covalent bonds
What are giant covalent substances? Give examples
- Solids , atoms covalently bonded together in a giant lattice
- High melting and boiling points - strong covalent bonds
- Mostly don’t conduct electricity (no delocalised electron)
- Diamond , graphite , silicon dioxide
Describe and explain the properties of allotropes of carbon - Diamond
- Four, strong covalent bonds for each carbon atom
- Very hard (strong bonds)
- Very high melting point (strong bonds)
- Does not conduct electricity (no delocalised electrons)
Describe and explain the properties of allotropes of carbon - Fullerenes
- hollow shaped molecules
- based on hexagonal rings but may have 5 or 7 - carbon rings
-The first fullerene to be discovered was Buckminsterfullerene (C60) which has a spherical shape.
Describe and explain the properties of allotropes of carbon - Graphite
- three covalent bonds for each carbon atom
- layers of hexagonal rings
- high melting point
- layers free to slide as weak intermolecular forces between layers; soft, can be used as lubricant
- conduct thermal and electricity due to one delocalised electron each carbon atom
Graphene - a single layer of graphite
Describe and explain the properties of allotropes of carbon - Nanotubes
- cylindrical fullerene with high length to diameter ratio
- high tensile strength (strong bonds)
- conduct electricity (delocalised electrons)
What is metallic bonding ?
Forces of attraction between delocalised electrons and nuclei of metal ions
Describe properties of metals
- high melting/boiling points (strong forces of attraction)
- good conductors of heat and electricity (delocalised electrons)
- Malleable , soft (layers of atoms can slide over eachother whilst maintaining the attraction forces)