Unit 1: Chemical Changes and Structure Flashcards

1
Q

What is collision theory?

A

Before a collision takes place, the particles must collide with each other and have the correct collision geometry.

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2
Q

What is an activated complex?

A

At the top of the activation barrier, a highly energetic species s formed.

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3
Q

What is the activation energy?

A

The minimum kinetic energy required by colliding molecules for a reaction to occur.

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4
Q

What is temperature?

A

The average kinetic energy of the particles in a substance.

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5
Q

What does a catalyst do?

A

It affects the activation energy by lowering it.

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6
Q

What is enthalpy?

A

A measure of the energy stored in a chemical (H).

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7
Q

What does an exothermic reaction do?

A

Gives out heat energy to the surrounding.
e.g combustion, displacement, neutralisation and respiration.
Enthalpy change is negative.
Products have less energy than reactants.

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8
Q

What does an endothermic reaction do?

A

Takes in heat from the surroundings.
e.g photosynthesis
Enthalpy change is positive.
Products have more energy than reactants.

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9
Q

What is a heterogeneous reaction?

A

The catalyst is in a different physical state from the reactants e.g solid catalysts such as metals speeding up the reaction of liquids or gases.

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10
Q

What is a homogeneous reaction?

A

The catalyst is in the same physical state as the reactants.

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11
Q

What is a catalyst?

A

A substance that speeds up the rate of reaction while remaining unchanged.

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12
Q

What is the bonding is metals?

A

The strength of metallic boding depends on the number of delocalised electrons per atom.
Increases along a period, decreases down a group.
Mp and Bp usually high.

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13
Q

What is the bonding in monatomic gases?

A

Nobles gases exist as single atoms with weak forces between them.

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14
Q

What is the bonding in covalent molecular?

A

Low Mp and Bp as only weak intermolecular forces between molecules need o be broken.
Exist as gases or liquids at room temperature

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15
Q

What is the bonding in covalent network?

A

High Mp and Bp- thousands.
Strong covalent bonds need to be broken.
Exist as solids.

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16
Q

How are the protons and electrons arranged in covalent, ionic and metallic bonds?

A

Covalent- Protons in nucleus, shared electrons.
Ionic- Protons in nucleus, lose or gain electrons.
Metallic- Protons in nucleus, delocalised electrons.

17
Q

What is the covalent radius?

A

Half the distance between the nuclei of two covalently bonded atoms.As you go down a group there is another shell of electrons and the size of the atoms increase.

18
Q

What is ionisation energy?

A

The first ionisation energy of an element is the energy required to remove one mole of electrons from one mole of atoms in the gaseous state.

19
Q

The strength of metallic bonding increases across a period because…

A

…more outer electrons become delocalised.

20
Q

The strength of metallic bonding decreases down a group because…

A

…you’re adding an extra energy level each time which creates more of a shield from the positive nucleus to the delocalised electrons.