Unit 12/13/14 Flashcards

0
Q

Fast diffusion

A

High to low concentration

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1
Q

Low density of liquid or solid

A

Liquid 1g/1000 cc

Solid 1g/cc

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2
Q

1 atm

A

760mm Hg or 760 torr

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3
Q

1 Pa

A

.0000009869 atm (6 zeros)

.00750 torr or mm Hg

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4
Q

Sea level=1 atm

A

760 torr=760 mm Hg=101.325 kPa=14.696 psi

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5
Q

Stp T

A

0 C or 273 K

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6
Q

Standard pressure 1 atm

A

760 torr or mm Hg=101.325 kPa

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7
Q

Standard molar volume

A

1 mole of any gas 22.4 L

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8
Q

Dalton’s partial pressure law

A

Total pressure is equal to sum of each gases partial pressure
Pt=Pa+Pb+Pc….+Pn

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9
Q

*Charles law V1/T2=

A

V2/T1

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10
Q

Boyles law P1V1=

A

P2V2

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11
Q

Combined gas laws

P1V1/T1=

A

P2V2/T2

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12
Q

PV=nRT

A
P=pressure in atm
V=volume in liters
n=number of moles
R=gas constant .0821L(atm)/mol(K)
T=temp in K
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13
Q

Molecular weight and density

D=MP/RT

A
M=molar mass 
D=density mass/volume
R=.0821
T=temp in K
P=pressure in atm
M=DRT/P
Remember HOFBRINCL
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14
Q

Graham’s law (effusion)

A

Rate a/rate b=sqrt(molar mass b/molar mass a)

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15
Q

Convert pressure to atmospheres

A

645 mm to atm

645 x 1 atm/760 mm = .85 atm

16
Q

Density in?

A

g/L

17
Q

Find mass using density formula

A

m=MPV/RT

18
Q

What type of equation?

An 800 mL sample of gas, measured at 44 C and 900 mm pressure. How many moles?

A

PV=nRT or n=PV/RT

19
Q

What type of equation?
Total pressure is 1.8 atm. Container contains 255 mm pressure due to N2, 518 mm pressure due to CO2 and in unknown pressure of CL2. What is the pressure due to the chlorine gas?

A

Pt=Pa+….Pc

Pt=760(1.8)-518-255=595 mm

20
Q

What type of equation?

What is the molecular weight of a gas that effuses 0.629 times as fast as O2.

A

Rate of a/rate of b=sqrt(Mb)/sqrt(Ma)

.629=sqrt(32g/mol)/x

21
Q

What type of equation?

What is the molecular weight of 3.47 g of a gas at 87 C with a volume of 3 L at a pressure of 1.4 atm?

A

D=PM/RT or M=DRT/P

22
Q

What type of equation?

What is the mass in grams of 1 L of methane (CH4) at STP?

A

m=MPV/RT

23
Q

What type of equation?

Convert to standard conditions: 1520 mL of gas at -33 C and 720 mm pressure.

A

V1P1T2=V2P2T1 or V1P1/T1=V2P2/T2

24
Q

What type of equation?

A sample of gas occupies 50 L at 27 C. What will be the volume of the gas in L at ST?

A

V1T2=V2T1

25
Q

What type of equation?

A gas has a volume of 240 mL at 70 cm pressure. What pressure, in cm is needed to reduce the volume to 60 mL.

A

V1P1=V2P2

26
Q

Mole-mole

How many moles of ammonia are produced when 6 moles of hydrogen gas react with an excess of nitrogen gas?

A

3H2+N2—>2NH3

6molH2 x 2mol NH3/3molH2= 4 mol NH3

27
Q

Mercury (ii) oxide

A

HgO

28
Q

Write the combustion reaction for pentane

A

C5H12—>5CO2+6H2O

29
Q

Limiting reactant

A

That amount of reactant that controls the amount produced. Completely consumed in the reaction.

30
Q

Excess reactant

A

Left over. Not completely consumed.

31
Q

Rules for finding limiting reactant

A

Solve both equations

-the one that produces the least is the limiting-correct amount

32
Q

Percent yield formula

A

Percent yield=actual/theoretical x 100

33
Q

Butane

A

C4H10

34
Q

Pentane

A

C5H12

35
Q

Stoichiometry and density in liquid and gas

A

Liquid g/mL

Gas g/L

36
Q

Stoichiometry molarity

A

Used when determining volume of aqueous solution. M=moles/Liter

37
Q

H is always terminal atom

A

Can only hold 2 electrons

38
Q

Central atom usually has lower

A

Electronegativity