. Flashcards
(24 cards)
‘Like dissolves ________’
Like
[Effect of Temperature on Solid in Liquid] When solubility increase as temp. increases the dissolution is________
Endothermic
Example: KCl, NaCl, NaNO3
[Effect of Temperature on Solid in Liquid] When solubility decrease as temp. increases the dissolution is________
Exothermic
Example: Na2CO3.H2O, Cerium Sulphate (Ce(SO4)3)
[Effect of Temperature on Solid in Liquid] Why does solubility does not continuously increase or decrease as temp. increases?
Because polymorphic/hydrated form changes to another
What is the effect of Pressure on solid in liquid solution?
no effect
[Gas in Liquid] Factor which affect the solubility of H2, He, N2 in H2O.
have small size therefore require less energy to vibrate.
[Effect of temperature Gas in Liquid] Dissolution if Gas in liquid is _______
Exothermic
[Effect of temperature Gas in Liquid] Solubility of some inert gases and H2 _____________ with increase in temp.
increases
[Effect of Pressure Gas in Liquid] State Henry’s Law
The partial pressure applied by any gas on a liquid surface is directly proportional to itsmole fractionpresent in a liquid solvent.
P= KHX
[Effect of Pressure Gas in Liquid] Relation between Henry’s constant and solubility.
Solubility ∝ 1/ KH
[Effect of Pressure Gas in Liquid] Unit of KH is
Same as Pressure
[Effect of Pressure Gas in Liquid] Relation between Henry’s constant and Temperature.
Temp ∝ KH
[Effect of Pressure Gas in Liquid] Conditon when Henry’s law is followed.
Pressure and Temperature is not too high.
Gas should not chemically react with solvent or not dissociate.
[Effect of Pressure Gas in Liquid] Gas responsible for Bends.
N2
[Effect of Pressure Gas in Liquid] Composition of gas in diver’s cylinder.
56.2% N2
11.7% He
32.1% O2
Vapour pressure does and does not depend on
1. Amount of Liquid
2. Temp.
3. Nature of Liquid
4. Shape and size of vessel
Depends on 1. and 4
Does not depend on 2 and 3
Relation between inter molecular forces of attraction in liquid and vapour pressure.
Inter molecular forces of attraction in liquid ∝ 1/vapour pressure.
Clauius Clapeyron Equation
Log(P2/ P1) = ΔHV/2.303R (1/T1 - 1/T2 )
Standard Boiling Point
Pext = 1 bar
Normal Boiling Point
Pext = 1 atm
State Raoult’s Law
The paritial V.P. of each component of a solution at constant temperature is directly proportional to its mole fraction
PA = PAo XA
Graph of Raoult’s Law when B is more Volatile
https://www.google.com/url?sa=i&url=https%3A%2F%2Funacademy.com%2Fcontent%2Fupsc%2Fstudy-material%2Fchemistry%2Fwhat-is-raoults-law%2F&psig=AOvVaw1O_gglteV22PaG-a0hzjcw&ust=1712981636143000&source=images&cd=vfe&opi=89978449&ved=0CBIQjRxqFwoTCLCmvIPou4UDFQAAAAAdAAAAABAE
Dalton’s Law Equation
PA = PT YA
Resulting equation of Dalton and Raoult’s Law.
YA/ PAo + YB/ PBo = 1/ PT