0.2 Quantum Phenomena Flashcards

1
Q

What is the photoelectric effect?

A

The photoelectric effect is a phenomenon in which, when certain types of light shines on a metal surface, electrons are ejected from it.

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2
Q

What did wave theory predict?

A

1) Any frequency (colour) of light should cause the photoelectric effect.

2) Increasing the intensity (brightness) of light should increase the energy of the electrons emitted.

3) It should take linger for electrons to be emitted when using low intensity light compared to high intensity light.

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3
Q

What actually happend (wave theory)?

A

1) Only above a certain ‘threshold’ frequency were electrons emitted.

2) As long as you are above the threshold frequency, increasing intensity increases the amount of electrons but their individual energy stayed the same.

3) The electrons were emitted instantly regardless of the intensity of light.

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4
Q

What was concluded (wave theory)?

A

1) Energy must be delivered in packets (particles), and must be proportional to the frequency of the wave. Electrons can’t store energy. Must be delivered all in one go.

2) There is a one-to-one ineteraction between a photon and an electron. The greater the intensity the more photons produced, therefore the greated the number of electrons emitted.

3) Energy must be delivered in packets in one go, rather than continuously. Electrons cannot store energy.

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5
Q

What is the work function?

A

The minimum amount of energy required for an electron to escape the surface of a metal.

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6
Q

What happens if hf < φ ?

A
  • Nothing will happen,
  • Increasing the intensity of the red light (producing more photons will also have no effect),
  • They cannot store energy.
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7
Q

What happens if hf = φ ?

A
  • An electron is released,
  • But with no kinetic energy,

-The frequency of this photon is known as the ‘threshold frequency’,

-The minimum frequency needed for an electron to escape the surface of a metal is called threshold frequency (fo).

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8
Q

What happens if hf < φ ?

A
  • Electron is released,
  • It leaves faster as the extra energy is transformed to kinetic energy,
  • We don’t release extra electrons as it is still only a 1 to 1 interaction.
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9
Q

Why do you see electrons released with a range of speed?

A

Because not all electrons are on the surface of the metal.
Those at deeper levels require more energy to esccape.

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10
Q

What would happen to the electrons if you double the intensity of light without changing the intensity of light without changing frequency?

A
  • Doubling the intensity of the light will double the number of photons incident on the surface of the metal.
  • Therefore DOUBLE the number of electrons are emitted.
  • But the Ek(max) will not change as each photon still carries the same amount of energy.
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11
Q

What is intensity?

A

The amount of energy arriving at every second per unit area.

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12
Q

How does the vaccum photocell (happy cyclops) work?

A

1) Photons release photoelectrons from the ‘smile’
2) They travel to the ‘eye’
3) Completing the circuit and creating a current

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13
Q

What happens when you add a power supply to a vaccum photocell?

A

1) When you increase the voltage the ‘eye’ becomes more negative and the ‘smile’ more positive.

2) This makes it harder for the electrons to escape; they are attracted back to the positive smile, and are repelled from the negative eye.

3) Initially only the electrons with small amount of Ek are pushed back.

4) Eventually if you turn up the voltage high enough all the electrons are pushed back and none cross the gap.

5) The current falls to zeron when even the electron with max kinetic energy are stopped.

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14
Q

How do you calculate the maximum kinetic energy of electrons using their charge and the voltage that stopped all of them?

A

eVs = Ek(max)
charge of an electron x stopping potential = Max kinetic energy

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15
Q

How can you make a gas glow?

A

By heating up / exciting the gas, it can cause it to glow.

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16
Q

How can you heat a gas to cause it to glow?

A

By passing a very high current through them, the high current is made up of fast-moving electrons.

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17
Q

What is a single colour actually made up of?

A

Multiple photons

18
Q

How can you see the multiple photons within a colour?

A

By splitting the light either by using a prism or a diffraction grating.

19
Q

What does the continuous spectrum consist of?

A

All the visible wavelengths.

20
Q

What happens when you take a gas, de-excite it (make it cold) and pass whitle light through it?

A

It will block certain photons, the photons it blocks are the same wavelength as the ones it emitted.

21
Q

What is the absorption spectrum?

A

Dark lines or gaps in the spectrum corresponding to wavelengths that are absorbed by the gas.

22
Q

Are the absorption and emission spectra different depending on the material?

A

Yes, still follows the rule of same photons being absorbed and emmited.

23
Q

What causes elements to both emit AND absorbe very specific photons?

A

Electrons

24
Q

Because of the photoelectric effect what do we know that electrons do?

A

Absorb and emit photons

25
Q

What causes electrons to only emit and absorb such specific amounts of energy?

A

They cannot exist in between energy levels; they can absorb energy and move up, OR emit energy and move down.

26
Q

What is n=1 known as?

A

The ground state

27
Q

What is the ground state?

A

This is where electrons have the least amount of energy / need to recive hte most energy to escape the atom. This is also where the electrons are the most stable.

28
Q

What is n=∞?

A

The ionisation level. This represents when an electron has left the atom entirely - turning the atom into an ion.

29
Q

How can electrons gain energy?

A

1) Absorb a photon (1 to 1 interaction)
2) Get hit with an external electron

30
Q

What is the ionisation energy?

A

The amount of energy needed to leave the atom from the ground state.

31
Q

When can an electron absorb a photon?

A

Only when a photon gives exactly the right amount of energy to move up 1 or more whole levels.
- CAN’T ABSORB HALF A PHOTON
Or with a collision with an electron where it van only absorb as much as ot needs.

32
Q

Why do we mark down the energy of each level as a negative?

A

Technically an electron which has left the atom has zero energy (used it all up to escape).

33
Q

Why do electrons not like being outside of the ground state?

A

> The ground state is where they have the least amount of energy and are most stable.

> The electrons will therefore return to the ground state by emitting energy.

> This energy is emitted as photons.

> Electrons can either return to the ground state in a single ‘jump’.

> Or cascade.

34
Q

What do energy levels explain?

A

Why elements have emission and absorption spectra, and why they are different for different elements.

35
Q

Fluorescent tubes step 1:

A

Flourescent tubes are filled with a mercury vapour.

36
Q

Fluorescent tubes step 2:

A

Apply a high potential difference across the tube.
This causes free electrons to rapidly accelerate from one side to the other.

37
Q

Fluorescent tubes step 3:

A

The free electrons collide with the ground state electrons in the mercury.
This excites them to a higher energy level.

38
Q

Fluorescent tubes step 4:

A

The excited electron will return to the ground state.
In doing so it releases a UV photon.
This is not visible to the naked eye.

39
Q

Fluorescent tubes step 5:

A

The tube is coated with a flourescent coating.
This turns the UV photon into visivle light.

40
Q

Fluorescent tubes step 6:

A

The UV photons will excite the electrons in the ground state of the coating to a higher energy level.

41
Q

Fluorescent tubes step 7:

A

The electrons cascades back down to the ground state.
Releasing lower energy photons which are in the visible part of the spectrum.
To our eyes it appeats white.

42
Q

What does flourescent mean?

A

Flourescent means it will glow when energy is given to it.