#1 Flashcards

(38 cards)

1
Q

What is kinetic energy

A

Energy of motion
+ anything moving has kinetic energy

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2
Q

What is potential energy

A
  • Stored energy
  • Dependant on condition of object
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3
Q

As soon as u start moving what happens to energy ?

A

Potential energy ~> Kinetic energy

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4
Q

Difference between uppercase Calorie and lowercase calorie???

A

Calorie (uppercase) = food calorie

calorie (lowercase) = thermal calorie

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5
Q

What is a joule & Kilo Joule ?

A

— Derived SI unit for energy
— its a v small amount of energy, so we use Kilo Joule

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6
Q

Unit conversions

1000 J = ___ KJ

A

1 KJ

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7
Q

UNIT CONVERSIONS

1 J = ___ cal

A

0.2390 cal

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8
Q

UNIT CONVERSIONS

4.18 J = ___ cal

A

1.00 cal (thermal) (3 sigfig)

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9
Q

Unit conversions

4.18 J = ___ Cal

A

1 Cal (food) (1 sigfig)

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10
Q

UNIT CONVERSIONS

1000 cal (thermal) = _____ Cal

A

= 1 Cal (food)

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11
Q

What is specific heat capacity?

A

Amount of energy (heat) needed to raise 1 gram of the substance by 1 degree Celsius

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12
Q

Formula for specific heat capacity ?

A

Heat capacity (C) = heat absorbed Q/ incr^ in temp T

— T can be (final T - initial T too)

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13
Q

Define Open system and give example

A

Can exchange BOTH ENERGY & MATTER w surroundings

Ex. An uncovered pot of potatoes boiling on the stove
=>The system absorbs energy from the stove burner. The system loses both energy and matter when the water evaporates out of the pan in the form of steam.

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14
Q

Define Closed system and give example

A

CAN exchange ENERGY NOT MATTER w/ surroundings

Ex. The pressure cooker with potatoes boiling on the stove
=> because pressure cookers are sealed. The sealed lid prevents the loss of mass, or water in the form of steam, but heat can still enter the system through contact of the pot bottom with the stove.

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15
Q

Isolated system

A

CANNOT exchange ENERGY AND MATTER w/ surroundings

Ex. A hot pan of food inside an insulated box
- no heat can go in or out
- no matter can leave the box either

Ex. the pot of potatoes inside an insulated container
=>The insulation prevents the exchange of any energy or matter between the system and its surroundings.

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16
Q

Universe =

A

System + surroundings

17
Q

Define system

A

Set of reactants + products being observed

18
Q

Define surroundings

A

Everything else

19
Q

What happens when a system and its surrounding interact

A

Energy and matter get exchanged

20
Q

Law of conservation of energy

A

Energy cannot be created or destroyed

it can only change form

21
Q

Good job!!

22
Q

Explain this:

Δ Etotal = Δ Esys + Δ Esurr = 0

A

total energy of the universe is a constant; if the system loses energy, it must be gained by the surroundings, and vice versa.

23
Q

Explain what each letter stands for and what we use this formula for

ΔQ = m . c . ΔT

A

Q = heat ethalpy (+ absorbed by the system / - left from system basically released)

M = mass

C= specific heat capacity

ΔT = change in temp
We find by (T final - T initial)

We use this to calculate amt of heat absorbed or released

24
Q

Solve

A 1.0 g sample of copper is heated from 25.0°C to 31.0°C. How much heat did the sample absorb? The specific heat capacity of copper is 0.385 J/g°C.

A

Given:

M = 1.0 g
C = 0.385/g°C
Δt = final - initial
31.0 - 25.0 = 6.00

Q = m.c.Δt
=1.0x0.385x6.00
=>2.3 J/g°C

25
Open closed or isolated The universe
Isolated
26
Open closed or isolated Ceramic mug of hot coca
Open
27
Open closed or isolated Sealed metal canister
Closed
28
Open closed or isolated An auto mobile with all doors, windows and vents closed Explain why as well here
Closed, not isolated as it can still exchange energy not matter (ie; absorb heat) from environment
29
Open closed or isolated A sealed insulated canister
Isolated
30
What does the first law of thermodynamics mean?
It means if a system undergoes a change that results in an increase or decrease in the amount of energy it has, That energy must have (come from or gone to)the surroundings
31
Explain ΔEuniverse = 0
- first law of thermodynamics states that the total energy of the universe is constant. - Energy is neither created nor destroyed; it is transformed from one type of energy to another or transferred from one object to another. So, change in the energy of the universe is zero. (Δ = change)
32
So, explain step by step Why is ΔEsys = -ΔEsurr
Since, when defining a system, the surroundings consist of everything else in the universe you could also say that the system plus the surroundings equals the universe — universe = system + surroundings the total energy of the universe is equal to the total energy of the system plus the total energy of the surroundings: Euniverse = Esystem +Esurroundings Similarly, any change in the total energy of the universe must be equal to the change in the total energy of the system + the change in the total energy of the surroundings. Since the change in the total energy of the universe is equal to zero, the following applies: ΔEuniverse = ΔEsystem + ΔEsurroundings = 0 By re-arranging this equation, any change in the total energy of the system must be equal and opposite to the change in the total energy of the surroundings: ΔEsystem = −ΔEsurroundings
33
Generally explain this ΔEsys = -ΔEsurr
In terms of practical situations such as warming soup on a stove, thawing ice, and any laboratory situation involving physical and chemical changes, the implications of the first law of thermodynamics are relatively straightforward: — for any system that gains energy, -> the energy must come from the surroundings — if any system loses energy, ->that energy must enter the surroundings.
34
Solve : A 25.00 g sample of water is heated to a temperature of 38.0°C, absorbing 2.96kJ of heat. What was the initial temperature of the water? The specific heat capacity of liquid water is 4.19 J/g°C.
ALWAYS NOTICE UNITS Given : (Change the units to match, turn them both into J) Q= 2.96 kJ —> 2980 J M = 25.00 J C= 4.19 J Rearrange formula To find time — Q = mcΔT -> ΔT = Q / m x c Sub in 2960 / 25 x 4.19 = ΔT 28.26 = ΔT ΔT = 28.26 Take the final temperature we are already given and subtract the change in temperature ΔT from it 38.0 - 28.26 = 9.7 initial temperature is 9.7°C
35
What is the first law of thermodynamics?
Energy can change form but can never be destroyed.
36
What is the second law of thermodynamics ?
When 2 objects are in thermal contact, heat is transferred from the object at a higher temp to the object at a lower temp until they are both the same temperature
37
What is thermal equilibrium
When both objects get to the same temp.
38
Why are the categories of enthalpy changes