1 Flashcards

(55 cards)

1
Q

What is the rate of a chemical reaction?

A

The speed or rate at which reactants are converted into products in a chemical reaction

It can be affected by factors such as concentration, temperature, pressure, and the presence of a catalyst.

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2
Q

What factors can affect the rate of a chemical reaction?

A
  • Concentration
  • Temperature
  • Pressure
  • Presence of a catalyst

These factors can alter the speed at which reactions occur.

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3
Q

What is the difference between average and instantaneous rates of reaction?

A

Average rate is calculated over a time interval, while instantaneous rate is the rate at a specific moment in time

Average rate gives a general speed, while instantaneous rate provides a precise measurement.

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4
Q

Give an example of a fast chemical reaction.

A

Precipitation of silver chloride by mixing aqueous solutions of silver nitrate and sodium chloride

This reaction occurs instantaneously.

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5
Q

Give an example of a slow chemical reaction.

A

Rusting of iron in the presence of air and moisture

This process takes a significant amount of time to occur.

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6
Q

What is the mathematical expression for the rate of reaction in terms of concentration?

A

Rate = Change in concentration of reactant or product per unit time

This can be expressed as the rate of disappearance of reactants or the rate of appearance of products.

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7
Q

What do the square brackets in the expressions for concentration represent?

A

Molar concentration of reactants and products

For example, [R] indicates the concentration of reactant R.

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8
Q

In a hypothetical reaction, what does one mole of reactant R produce?

A

One mole of product P

This is a basic stoichiometric relationship in chemical reactions.

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9
Q

Fill in the blank: The rate of disappearance of reactant R is measured as _______.

A

the change in concentration of R over time

This is crucial for calculating the overall reaction rate.

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10
Q

True or False: The rate of a reaction can vary depending on the conditions under which it occurs.

A

True

Different conditions such as temperature and concentration can significantly alter the reaction rate.

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11
Q

What is a collision theory in the context of reaction rates?

A

A theory that explains how the orientation and energy of molecules during collisions affect the rate of reaction

This theory helps in understanding the mechanisms behind chemical reactions.

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12
Q

What is chemical kinetics?

A

The study of the rates of chemical reactions and the factors affecting them.

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13
Q

True or False: The rate of a reaction is constant throughout the reaction.

A

False

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14
Q

What factors affect the rate of a chemical reaction?

A

Concentration, temperature, surface area, and the presence of catalysts.

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15
Q

Fill in the blank: The rate of reaction increases with an increase in ___.

A

temperature

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16
Q

Define ‘reaction rate’.

A

The change in concentration of a reactant or product per unit time.

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17
Q

What is the unit of reaction rate?

A

mol L^-1 s^-1

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18
Q

How does concentration affect the rate of reaction?

A

Increasing the concentration of reactants generally increases the reaction rate.

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19
Q

What is the role of a catalyst in a chemical reaction?

A

A catalyst increases the rate of a reaction without being consumed in the process.

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20
Q

True or False: Catalysts change the equilibrium constant of a reaction.

A

False

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21
Q

What does the rate law expression represent?

A

The relationship between the rate of a reaction and the concentration of its reactants.

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22
Q

What is the general form of a rate law expression?

A

Rate = k[A]^m[B]^n

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23
Q

Define the term ‘order of reaction’.

A

The sum of the powers of the concentration terms in the rate law.

24
Q

What is zero-order reaction?

A

A reaction whose rate does not depend on the concentration of reactants.

25
Give an example of a first-order reaction.
Radioactive decay.
26
What is the half-life of a reaction?
The time required for the concentration of a reactant to decrease to half its initial value.
27
True or False: The half-life of a first-order reaction depends on the initial concentration.
False
28
What is an Arrhenius equation?
An equation that shows the relationship between the rate constant and temperature.
29
What is the activation energy?
The minimum energy required for a reaction to occur.
30
Fill in the blank: The rate constant (k) increases with an increase in ___.
temperature
31
What is a reaction mechanism?
The step-by-step sequence of elementary reactions by which overall chemical change occurs.
32
True or False: A slow step in a reaction mechanism is called the rate-determining step.
True
33
Define 'intermediate' in the context of chemical kinetics.
A species that is formed in one step of a reaction mechanism and consumed in another.
34
What is the effect of surface area on the rate of reaction?
Increasing surface area increases the rate of reaction.
35
What type of reaction is characterized by a rate that depends on the concentration of only one reactant?
First-order reaction.
36
What is the significance of the rate constant (k)?
It indicates the speed of the reaction at a given temperature.
37
What is a second-order reaction?
A reaction whose rate depends on the square of the concentration of one reactant or the product of the concentrations of two reactants.
38
Fill in the blank: The rate of a zero-order reaction is independent of the concentration of ___.
reactants
39
What is a complex reaction?
A reaction that involves multiple elementary steps.
40
True or False: The rate of reaction can be affected by the physical state of reactants.
True
41
Define 'homogeneous catalyst'.
A catalyst that is in the same phase as the reactants.
42
What is a heterogeneous catalyst?
A catalyst that is in a different phase from the reactants.
43
What is meant by 'temperature coefficient'?
The factor by which the rate of reaction increases with a 10°C rise in temperature.
44
Fill in the blank: The temperature coefficient for most reactions is approximately ___.
2
45
What does the term 'steady-state approximation' refer to?
An assumption that the concentration of intermediates remains constant during the reaction.
46
What is the effect of pressure on the rate of reaction involving gases?
Increasing pressure increases the rate of reaction by increasing the concentration of gases.
47
True or False: In a first-order reaction, the concentration of reactants decreases exponentially over time.
True
48
What is meant by 'rate constant'?
A proportionality factor in the rate law that is specific to a given reaction at a specified temperature.
49
How does the presence of a catalyst influence the activation energy?
A catalyst lowers the activation energy required for the reaction.
50
Fill in the blank: A reaction that proceeds through a single step is called a ___.
single-step reaction
51
What is the significance of the collision theory?
It explains how chemical reactions occur and why reaction rates differ.
52
What is the role of molecular orientation in a chemical reaction?
Proper orientation of reactant molecules is necessary for effective collisions and reactions to occur.
53
True or False: All collisions between reactant molecules lead to a reaction.
False
54
What is a chain reaction?
A reaction that proceeds through a series of steps, with free radicals generated that propagate the reaction.
55
Define 'transition state'.
A temporary state during a reaction where the reactants are in the process of being converted to products.